Magnetic properties of single-crystalline preferential {001}-oriented Bi2Fe4O9nanosheets with thickness of about 13 nm, synthesized via a facile hydrothermal method, have been investigated through variable temperature...Magnetic properties of single-crystalline preferential {001}-oriented Bi2Fe4O9nanosheets with thickness of about 13 nm, synthesized via a facile hydrothermal method, have been investigated through variable temperature electron spin resonance measurement. A typical ferromagnetic state could be appeared in the measured temperature from 110 K to 300 K and the origin would be contributed to uncompensated surface spin due to its large surface-to-volume ratio and/or a few non-detectable impurities with strong magnetism. Interestingly, another weak ferromagnetic state could present below the temperature about 250 K, indicative of Neel temperature (TN) of antiferromagnetic state, which is slightly lower than that of bulksample of 265 K.展开更多
Synthesis of a novel α phosphorus containing spin trap, DEPPEPO[5 (diethoxyphosphoryl) 5 phenylethyl 1 pyrroline] N oxide and evaluation of its ability to spin trap the hydroxyl and the superoxide anion radicals were...Synthesis of a novel α phosphorus containing spin trap, DEPPEPO[5 (diethoxyphosphoryl) 5 phenylethyl 1 pyrroline] N oxide and evaluation of its ability to spin trap the hydroxyl and the superoxide anion radicals were described in the present article. The ability for trapping an active superoxide anion radicals generated in the HX/XO system and the stability of their spin adduct of DEPPEPO were analyzed. In addition, the effects of 5 phenylethyl and 5 phenyl substituted analogues of DMPO on the stereochemistry of the corresponding spin adducts were systematically illustrated.展开更多
文摘Magnetic properties of single-crystalline preferential {001}-oriented Bi2Fe4O9nanosheets with thickness of about 13 nm, synthesized via a facile hydrothermal method, have been investigated through variable temperature electron spin resonance measurement. A typical ferromagnetic state could be appeared in the measured temperature from 110 K to 300 K and the origin would be contributed to uncompensated surface spin due to its large surface-to-volume ratio and/or a few non-detectable impurities with strong magnetism. Interestingly, another weak ferromagnetic state could present below the temperature about 250 K, indicative of Neel temperature (TN) of antiferromagnetic state, which is slightly lower than that of bulksample of 265 K.
文摘Synthesis of a novel α phosphorus containing spin trap, DEPPEPO[5 (diethoxyphosphoryl) 5 phenylethyl 1 pyrroline] N oxide and evaluation of its ability to spin trap the hydroxyl and the superoxide anion radicals were described in the present article. The ability for trapping an active superoxide anion radicals generated in the HX/XO system and the stability of their spin adduct of DEPPEPO were analyzed. In addition, the effects of 5 phenylethyl and 5 phenyl substituted analogues of DMPO on the stereochemistry of the corresponding spin adducts were systematically illustrated.
