Nitrogen doping in chemical vapor deposition-derived ultrananocrystalline diamond(UNCD)films in-creases the electronic conductivity,yet its microstructural effects on electron transport are insufficiently understood.W...Nitrogen doping in chemical vapor deposition-derived ultrananocrystalline diamond(UNCD)films in-creases the electronic conductivity,yet its microstructural effects on electron transport are insufficiently understood.We investigated the formation of nitrogen-induced diaph-ite structures(hybrid diamond-graphite phases)and their role in changing the conductivity.Nitrogen doping in a hy-drogen-rich plasma environment promotes the emergence of unique sp^(3)-sp^(2)bonding interfaces,where diamond grains are covalently integrated with graphitic domains,facilitating a structure-driven electronic transition.High-resolution transmis-sion electron microscopy and selected area electron diffraction reveal five-fold,six-fold and twelve-fold symmetries,along with an atypical{200}crystallographic reflection,confirming diaphite formation in 5%and 10%N-doped UNCD films,while high-er doping levels(15%and 20%)result in extensive graphitization.Raman spectroscopy tracks the evolution of sp^(2)bonding with increasing nitrogen content,while atomic force microscopy and X-ray diffraction indicate a consistent diamond grain size of~8 nm.Cryogenic electronic transport measurements reveal a conductivity increase from 8.72 to 708 S/cm as the nitrogen dop-ing level increases from 5%to 20%,which is attributed to defect-mediated carrier transport and 3D weak localization.The res-ulting conductivity is three orders of magnitude higher than previously reported.These findings establish a direct correlation between diaphite structural polymorphism and tunable electronic properties in nitrogen-doped UNCD films,offering new ways for defect-engineering diamond-based electronic materials.展开更多
Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown tha...Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown that this structure gives it exceptional physical properties that exceed those of cubic diamond,making it highly promising for groundbreaking applications in superhard cutting tools,wide-bandgap semiconductor devices,and materials for extreme environments.As a result,the controllable synthesis of hexagonal diamond has emerged as a cutting-edge research focus in materials science.This review briefly outlines the progress in this area,with a focus on the mechanisms governing its key synthesis conditions,its intrinsic physical properties,and its potential applications in various fields.展开更多
Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity ar...Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity are also tunable,increasing its functional versatility.These make diamond and its related materials,such as its composites,highly promising for various applications in energy fields.This review summarizes recent advances and key achievements in energy storage and conversion,covering electrochemical energy storage(e.g.,batteries and supercapacitors),electrocatalytic energy conversion(e.g.,CO_(2)and nitrogen reduction reactions),and solar energy conversion(e.g.,photo-(electro)chemical CO_(2)and nitrogen reduction reactions,and solar cells).Current challenges and prospects related to the synthesis of diamond materials and the technologies for their energy applications are outlined and discussed.展开更多
A fast encoding algorithm based on the mean square error （MSE） distortion for vector quantization is introduced. The vector, which is effectively constructed with wavelet transform （WT） coefficients of images, can...A fast encoding algorithm based on the mean square error （MSE） distortion for vector quantization is introduced. The vector, which is effectively constructed with wavelet transform （WT） coefficients of images, can simplify the realization of the non-linear interpolated vector quantization （NLIVQ） technique and make the partial distance search （PDS） algorithm more efficient. Utilizing the relationship of vector L2-norm and its Euclidean distance, some conditions of eliminating unnecessary codewords are obtained. Further, using inequality constructed by the subvector L2-norm, more unnecessary codewords are eliminated. During the search process for code, mostly unlikely codewords can be rejected by the proposed algorithm combined with the non-linear interpolated vector quantization technique and the partial distance search technique. The experimental results show that the reduction of computation is outstanding in the encoding time and complexity against the full search method.展开更多
In order to optionally regulate embedding capacity and embedding transparency according to user's requirements in voice-over-IP(VoIP) steganography,a dynamic matrix encoding strategy(DMES) was presented.Differing ...In order to optionally regulate embedding capacity and embedding transparency according to user's requirements in voice-over-IP(VoIP) steganography,a dynamic matrix encoding strategy(DMES) was presented.Differing from the traditional matrix encoding strategy,DMES dynamically chose the size of each message group in a given set of adoptable message sizes.The appearance possibilities of all adoptable sizes were set in accordance with the desired embedding performance(embedding rate or bit-change rate).Accordingly,a searching algorithm that could provide an optimal combination of appearance possibilities was proposed.Furthermore,the roulette wheel algorithm was employed to determine the size of each message group according to the optimal combination of appearance possibilities.The effectiveness of DMES was evaluated in StegVoIP,which is a typical covert communication system based on VoIP.The experimental results demonstrate that DMES can adjust embedding capacity and embedding transparency effectively and flexibly,and achieve the desired embedding performance in any case.For the desired embedding rate,the average errors are not more than 0.000 8,and the standard deviations are not more than 0.002 0;for the desired bit-change rate,the average errors are not more than 0.001 4,and the standard deviations are not more than 0.002 6.展开更多
Oncolysate, a debris of tumor cells, has been provento be effective in tumor active immunotherapy, it wasreported that the vaccinia virus, especially recombinantvaccinia viruses encoding human IL-2 (rVV-IL-2 ),enhance...Oncolysate, a debris of tumor cells, has been provento be effective in tumor active immunotherapy, it wasreported that the vaccinia virus, especially recombinantvaccinia viruses encoding human IL-2 (rVV-IL-2 ),enhanced the immunogenicity of transfected tumor cells.In this experiment, the murine melanoma cell B16-F10oncolysates trans fected by rVV-IL-2 (IL-2VBO) wereused as vaccine. The IL-2VBO or TK-VBO was preparedby incubating B16-F10 cells with rVV-IL-2 or rVV-TK展开更多
Fountain codes are considered to be a promising coding technique in underwater acoustic communication（UAC） which is challenged with the unique propagation features of the underwater acoustic channel and the harsh ma...Fountain codes are considered to be a promising coding technique in underwater acoustic communication（UAC） which is challenged with the unique propagation features of the underwater acoustic channel and the harsh marine environment. And Luby transform（LT） codes are the first codes fully realizing the digital fountain concept. However, in conventional LT encoding/decoding algorithms, due to the imperfect coverage（IC） of input symbols and short cycles in the generator matrix, stopping sets would occur and terminate the decoding. Thus, the recovery probability is reduced,high coding overhead is required and decoding delay is increased.These issues would be disadvantages while applying LT codes in underwater acoustic communication. Aimed at solving those issues, novel encoding/decoding algorithms are proposed. First,a doping and non-uniform selecting（DNS） encoding algorithm is proposed to solve the IC and the generation of short cycles problems. And this can reduce the probability of stopping sets occur during decoding. Second, a hybrid on the fly Gaussian elimination and belief propagation（OFG-BP） decoding algorithm is designed to reduce the decoding delay and efficiently utilize the information of stopping sets. Comparisons via Monte Carlo simulation confirm that the proposed schemes could achieve better overall decoding performances in comparison with conventional schemes.展开更多
A predicted tau glutathione S-transferase(GST) subunit encoding gene,named GhGST,was isolated from Gossypium hirsutum with RACE method from SSH library based on Verticillium
Direct gene transfer into somatic tissue in vivo is adeveloping technology with potential application forcancer gene therapy. Retrovirus vector, which was aneffective vehicle, still has some disadvantages ingenerating...Direct gene transfer into somatic tissue in vivo is adeveloping technology with potential application forcancer gene therapy. Retrovirus vector, which was aneffective vehicle, still has some disadvantages ingenerating high titer recombinant vectors andmanipulating to mediate in viro gene transfer. In thispaper, recombinant vaccinia virus vector encoding展开更多
We have constructed three recombinantadenoviruses encoding RA538, p53 or p16 respec-tively. These recombinant adenoviruses are able toexpress RA538, p53 or p16 in infected human cancercells. The transduction efficienc...We have constructed three recombinantadenoviruses encoding RA538, p53 or p16 respec-tively. These recombinant adenoviruses are able toexpress RA538, p53 or p16 in infected human cancercells. The transduction efficiency assay showed thatthe infected cancer cells inoculated with theserecombinant adenoviruses at MOI of 25 or greaterexhibited 100% transduction efficiency. The growthrates and colony formation of cancer cells infectedwith these recombinant adenoviruses were展开更多
To improve the error correction performance, an innovative encoding structure with tail-biting for spinal codes is designed. Furthermore, an adaptive forward stack decoding(A-FSD) algorithm with lower complexity for s...To improve the error correction performance, an innovative encoding structure with tail-biting for spinal codes is designed. Furthermore, an adaptive forward stack decoding(A-FSD) algorithm with lower complexity for spinal codes is proposed. In the A-FSD algorithm, a flexible threshold parameter is set by a variable channel state to narrow the scale of nodes accessed. On this basis, a new decoding method of AFSD with early termination(AFSD-ET) is further proposed. The AFSD-ET decoder not only has the ability of dynamically modifying the number of stored nodes, but also adopts the early termination criterion to curtail complexity. The complexity and related parameters are verified through a series of simulations. The simulation results show that the proposed spinal codes with tail-biting and the AFSD-ET decoding algorithms can reduce the complexity and improve the decoding rate without sacrificing correct decoding performance.展开更多
Plants have developed a complicated defense mechanism during evolution to resist the harmful pathogens they encountered.The mechanism involves the interaction of the plant resistance(R)
文摘Nitrogen doping in chemical vapor deposition-derived ultrananocrystalline diamond(UNCD)films in-creases the electronic conductivity,yet its microstructural effects on electron transport are insufficiently understood.We investigated the formation of nitrogen-induced diaph-ite structures(hybrid diamond-graphite phases)and their role in changing the conductivity.Nitrogen doping in a hy-drogen-rich plasma environment promotes the emergence of unique sp^(3)-sp^(2)bonding interfaces,where diamond grains are covalently integrated with graphitic domains,facilitating a structure-driven electronic transition.High-resolution transmis-sion electron microscopy and selected area electron diffraction reveal five-fold,six-fold and twelve-fold symmetries,along with an atypical{200}crystallographic reflection,confirming diaphite formation in 5%and 10%N-doped UNCD films,while high-er doping levels(15%and 20%)result in extensive graphitization.Raman spectroscopy tracks the evolution of sp^(2)bonding with increasing nitrogen content,while atomic force microscopy and X-ray diffraction indicate a consistent diamond grain size of~8 nm.Cryogenic electronic transport measurements reveal a conductivity increase from 8.72 to 708 S/cm as the nitrogen dop-ing level increases from 5%to 20%,which is attributed to defect-mediated carrier transport and 3D weak localization.The res-ulting conductivity is three orders of magnitude higher than previously reported.These findings establish a direct correlation between diaphite structural polymorphism and tunable electronic properties in nitrogen-doped UNCD films,offering new ways for defect-engineering diamond-based electronic materials.
基金the National Natural Science Foundation of China(12274170 and 52225203)。
文摘Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown that this structure gives it exceptional physical properties that exceed those of cubic diamond,making it highly promising for groundbreaking applications in superhard cutting tools,wide-bandgap semiconductor devices,and materials for extreme environments.As a result,the controllable synthesis of hexagonal diamond has emerged as a cutting-edge research focus in materials science.This review briefly outlines the progress in this area,with a focus on the mechanisms governing its key synthesis conditions,its intrinsic physical properties,and its potential applications in various fields.
基金西南大学中央高校基本科研业务费项目(SWU-KT22030)重庆市教育委员会科学技术研究项目(KJQN202300205)Deutsche Forschungsgemeinschaft(DFG,German Research Foundation,457444676).
文摘Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity are also tunable,increasing its functional versatility.These make diamond and its related materials,such as its composites,highly promising for various applications in energy fields.This review summarizes recent advances and key achievements in energy storage and conversion,covering electrochemical energy storage(e.g.,batteries and supercapacitors),electrocatalytic energy conversion(e.g.,CO_(2)and nitrogen reduction reactions),and solar energy conversion(e.g.,photo-(electro)chemical CO_(2)and nitrogen reduction reactions,and solar cells).Current challenges and prospects related to the synthesis of diamond materials and the technologies for their energy applications are outlined and discussed.
基金the National Natural Science Foundation of China (60602057)the NaturalScience Foundation of Chongqing Science and Technology Commission (2006BB2373).
文摘A fast encoding algorithm based on the mean square error （MSE） distortion for vector quantization is introduced. The vector, which is effectively constructed with wavelet transform （WT） coefficients of images, can simplify the realization of the non-linear interpolated vector quantization （NLIVQ） technique and make the partial distance search （PDS） algorithm more efficient. Utilizing the relationship of vector L2-norm and its Euclidean distance, some conditions of eliminating unnecessary codewords are obtained. Further, using inequality constructed by the subvector L2-norm, more unnecessary codewords are eliminated. During the search process for code, mostly unlikely codewords can be rejected by the proposed algorithm combined with the non-linear interpolated vector quantization technique and the partial distance search technique. The experimental results show that the reduction of computation is outstanding in the encoding time and complexity against the full search method.
基金Project(2009AA01A402) supported by the National High-Tech Research and Development Program of ChinaProject(NCET-06-0650) supported by Program for New Century Excellent Talents in University Project(IRT-0725) supported by Program for Changjiang Scholars and Innovative Research Team in Chinese University
文摘In order to optionally regulate embedding capacity and embedding transparency according to user's requirements in voice-over-IP(VoIP) steganography,a dynamic matrix encoding strategy(DMES) was presented.Differing from the traditional matrix encoding strategy,DMES dynamically chose the size of each message group in a given set of adoptable message sizes.The appearance possibilities of all adoptable sizes were set in accordance with the desired embedding performance(embedding rate or bit-change rate).Accordingly,a searching algorithm that could provide an optimal combination of appearance possibilities was proposed.Furthermore,the roulette wheel algorithm was employed to determine the size of each message group according to the optimal combination of appearance possibilities.The effectiveness of DMES was evaluated in StegVoIP,which is a typical covert communication system based on VoIP.The experimental results demonstrate that DMES can adjust embedding capacity and embedding transparency effectively and flexibly,and achieve the desired embedding performance in any case.For the desired embedding rate,the average errors are not more than 0.000 8,and the standard deviations are not more than 0.002 0;for the desired bit-change rate,the average errors are not more than 0.001 4,and the standard deviations are not more than 0.002 6.
文摘Oncolysate, a debris of tumor cells, has been provento be effective in tumor active immunotherapy, it wasreported that the vaccinia virus, especially recombinantvaccinia viruses encoding human IL-2 (rVV-IL-2 ),enhanced the immunogenicity of transfected tumor cells.In this experiment, the murine melanoma cell B16-F10oncolysates trans fected by rVV-IL-2 (IL-2VBO) wereused as vaccine. The IL-2VBO or TK-VBO was preparedby incubating B16-F10 cells with rVV-IL-2 or rVV-TK
基金supported by the National Natural Science Foundation of China(61371099)the Fundamental Research Funds for the Central Universities of China(HEUCF150812/150810)
文摘Fountain codes are considered to be a promising coding technique in underwater acoustic communication（UAC） which is challenged with the unique propagation features of the underwater acoustic channel and the harsh marine environment. And Luby transform（LT） codes are the first codes fully realizing the digital fountain concept. However, in conventional LT encoding/decoding algorithms, due to the imperfect coverage（IC） of input symbols and short cycles in the generator matrix, stopping sets would occur and terminate the decoding. Thus, the recovery probability is reduced,high coding overhead is required and decoding delay is increased.These issues would be disadvantages while applying LT codes in underwater acoustic communication. Aimed at solving those issues, novel encoding/decoding algorithms are proposed. First,a doping and non-uniform selecting（DNS） encoding algorithm is proposed to solve the IC and the generation of short cycles problems. And this can reduce the probability of stopping sets occur during decoding. Second, a hybrid on the fly Gaussian elimination and belief propagation（OFG-BP） decoding algorithm is designed to reduce the decoding delay and efficiently utilize the information of stopping sets. Comparisons via Monte Carlo simulation confirm that the proposed schemes could achieve better overall decoding performances in comparison with conventional schemes.
文摘A predicted tau glutathione S-transferase(GST) subunit encoding gene,named GhGST,was isolated from Gossypium hirsutum with RACE method from SSH library based on Verticillium
文摘Direct gene transfer into somatic tissue in vivo is adeveloping technology with potential application forcancer gene therapy. Retrovirus vector, which was aneffective vehicle, still has some disadvantages ingenerating high titer recombinant vectors andmanipulating to mediate in viro gene transfer. In thispaper, recombinant vaccinia virus vector encoding
文摘We have constructed three recombinantadenoviruses encoding RA538, p53 or p16 respec-tively. These recombinant adenoviruses are able toexpress RA538, p53 or p16 in infected human cancercells. The transduction efficiency assay showed thatthe infected cancer cells inoculated with theserecombinant adenoviruses at MOI of 25 or greaterexhibited 100% transduction efficiency. The growthrates and colony formation of cancer cells infectedwith these recombinant adenoviruses were
基金supported by the National Natural Science Foundation of China (61701020)the Scientific and Technological Innovation Foundation of Shunde Graduate School,USTB (BK19BF009)。
文摘To improve the error correction performance, an innovative encoding structure with tail-biting for spinal codes is designed. Furthermore, an adaptive forward stack decoding(A-FSD) algorithm with lower complexity for spinal codes is proposed. In the A-FSD algorithm, a flexible threshold parameter is set by a variable channel state to narrow the scale of nodes accessed. On this basis, a new decoding method of AFSD with early termination(AFSD-ET) is further proposed. The AFSD-ET decoder not only has the ability of dynamically modifying the number of stored nodes, but also adopts the early termination criterion to curtail complexity. The complexity and related parameters are verified through a series of simulations. The simulation results show that the proposed spinal codes with tail-biting and the AFSD-ET decoding algorithms can reduce the complexity and improve the decoding rate without sacrificing correct decoding performance.
文摘Plants have developed a complicated defense mechanism during evolution to resist the harmful pathogens they encountered.The mechanism involves the interaction of the plant resistance(R)
