基于室内物理模型试验和原位锚固试验,对基于高模数硅酸钾溶液-（粉煤灰＋粉土）（PS-（F＋C））浆液的木锚杆锚固系统在夯土介质中进行了拉拔测试与杆体-浆体界面应变监测,研究了该锚固系统的锚固性能与破坏模式、杆体-浆体界面剪应力...基于室内物理模型试验和原位锚固试验,对基于高模数硅酸钾溶液-（粉煤灰＋粉土）（PS-（F＋C））浆液的木锚杆锚固系统在夯土介质中进行了拉拔测试与杆体-浆体界面应变监测,研究了该锚固系统的锚固性能与破坏模式、杆体-浆体界面剪应力分布与传递特征。结果表明：该锚固系统室内试验极限锚固力（24～38 k N）远大于现场试验值（2.5～8 k N）;锚固系统具有低弹性强塑性特征,表现出极强的延性;在荷载进程中杆体-浆体界面的应力分布与传递特征具有多峰值分布、高值往往出现在锚固末端、压应力出现等特征,表明该锚固系统兼有拉力型和压力型全长黏结性锚固系统的特点;该系统适合于夯筑土遗址锚固,与遗址具有良好的物理力学兼容性。展开更多
Oxidation process of Co(C 6 H 11 O) 2 PS 2 2 and substitute-reduction reaction of Co C 6 H 11 O) 2 PS 2 3 with pyridine have been studied by spectrophotome tric methods,respectively.The equ ilibrium constant was found...Oxidation process of Co(C 6 H 11 O) 2 PS 2 2 and substitute-reduction reaction of Co C 6 H 11 O) 2 PS 2 3 with pyridine have been studied by spectrophotome tric methods,respectively.The equ ilibrium constant was found to be K=0.63±0.02(mol·dm -3 ) -3 .The crystal structure of Co 6 H 11 O) 2 PS 2 2·2Py has been determined by X-ray diff-raction method.The crystal belongs to triclinic system,space groupP1,with cell parameters:a=6.944(2)?,b=9.277(3)?,c=15.981(6)?,α=91.79(3)°,β=99.55(3)°,γ=94.44(3)°,V=1011.2(6)? 3 ,Z =2,M r =803.94,D c =1.320Mg ·m -3 ,F(000)=425,μ=0.747mm -1 ,final R=0.0700and w R=0.1988for 3626re-flections with I≥2σ(I).The cobalt atom in the title complex has a octahedral geometry with four Co-S bonds and two Co-N bonds.The central atom P is t etrahedrally surrounded by two sulp hur atoms and two oxygen atoms in the dicyclohexyldithiophosphate liga nd.The six carbon atoms of cyclohexyl take the chair conformation.展开更多
Additive reactions of Ni[(C 4H 9O) 2PS 2] 2 with ethylamine,diethylamine and triethylamine were studied by spectrophotometric methods in ethanol at several tempertures.With ethylamine,the adduct formation of NiL 2...Additive reactions of Ni[(C 4H 9O) 2PS 2] 2 with ethylamine,diethylamine and triethylamine were studied by spectrophotometric methods in ethanol at several tempertures.With ethylamine,the adduct formation of NiL 2·B and NiL 2·B 2 was established.For diethylamine and triethylamine,being of their steric hindrance effect,the formation of NiL 2·B only was concluded.Their additive equilibrium constants(lg β n)and additive molecular number(n) were discussed.Thermodynamic parameters △ r H m and △ r S m were found by the least square method.The additive equilibrium constants in the range 278 0～303 0K were described by empirical equation.展开更多
研究大气CO2浓度升高对绿豆生长及C、N吸收的影响,有助于了解未来气候变化下绿豆养分平衡的变化。利用FACE(Free Air CO2 Enrichment)系统在大田条件下研究了CO2浓度升高对绿豆生物量及C、N吸收的影响。结果表明:大气CO2浓度升高使绿豆...研究大气CO2浓度升高对绿豆生长及C、N吸收的影响,有助于了解未来气候变化下绿豆养分平衡的变化。利用FACE(Free Air CO2 Enrichment)系统在大田条件下研究了CO2浓度升高对绿豆生物量及C、N吸收的影响。结果表明:大气CO2浓度升高使绿豆叶、茎、荚、根、地上部分生物量、总生物量及根冠比增加。各发育期地上部分含N量下降10.39%～21.06%,含C量增加0.41%～1.13%,C/N增加12.23%～26.68%;籽粒中N、C含量及C/N无显著变化。植株地上部分吸N量和吸C量分别增加1.99%～50.87%和14.43%～92.69%。未来大气CO2浓度升高条件下,绿豆将通过生物量的增加固定更多的C,并增加对N素的吸收,未来的绿豆生产应考虑增加土壤的施肥水平以保证其养分供应。展开更多
文摘基于室内物理模型试验和原位锚固试验,对基于高模数硅酸钾溶液-（粉煤灰＋粉土）（PS-（F＋C））浆液的木锚杆锚固系统在夯土介质中进行了拉拔测试与杆体-浆体界面应变监测,研究了该锚固系统的锚固性能与破坏模式、杆体-浆体界面剪应力分布与传递特征。结果表明：该锚固系统室内试验极限锚固力（24～38 k N）远大于现场试验值（2.5～8 k N）;锚固系统具有低弹性强塑性特征,表现出极强的延性;在荷载进程中杆体-浆体界面的应力分布与传递特征具有多峰值分布、高值往往出现在锚固末端、压应力出现等特征,表明该锚固系统兼有拉力型和压力型全长黏结性锚固系统的特点;该系统适合于夯筑土遗址锚固,与遗址具有良好的物理力学兼容性。
文摘Oxidation process of Co(C 6 H 11 O) 2 PS 2 2 and substitute-reduction reaction of Co C 6 H 11 O) 2 PS 2 3 with pyridine have been studied by spectrophotome tric methods,respectively.The equ ilibrium constant was found to be K=0.63±0.02(mol·dm -3 ) -3 .The crystal structure of Co 6 H 11 O) 2 PS 2 2·2Py has been determined by X-ray diff-raction method.The crystal belongs to triclinic system,space groupP1,with cell parameters:a=6.944(2)?,b=9.277(3)?,c=15.981(6)?,α=91.79(3)°,β=99.55(3)°,γ=94.44(3)°,V=1011.2(6)? 3 ,Z =2,M r =803.94,D c =1.320Mg ·m -3 ,F(000)=425,μ=0.747mm -1 ,final R=0.0700and w R=0.1988for 3626re-flections with I≥2σ(I).The cobalt atom in the title complex has a octahedral geometry with four Co-S bonds and two Co-N bonds.The central atom P is t etrahedrally surrounded by two sulp hur atoms and two oxygen atoms in the dicyclohexyldithiophosphate liga nd.The six carbon atoms of cyclohexyl take the chair conformation.
文摘Additive reactions of Ni[(C 4H 9O) 2PS 2] 2 with ethylamine,diethylamine and triethylamine were studied by spectrophotometric methods in ethanol at several tempertures.With ethylamine,the adduct formation of NiL 2·B and NiL 2·B 2 was established.For diethylamine and triethylamine,being of their steric hindrance effect,the formation of NiL 2·B only was concluded.Their additive equilibrium constants(lg β n)and additive molecular number(n) were discussed.Thermodynamic parameters △ r H m and △ r S m were found by the least square method.The additive equilibrium constants in the range 278 0～303 0K were described by empirical equation.
文摘研究大气CO2浓度升高对绿豆生长及C、N吸收的影响,有助于了解未来气候变化下绿豆养分平衡的变化。利用FACE(Free Air CO2 Enrichment)系统在大田条件下研究了CO2浓度升高对绿豆生物量及C、N吸收的影响。结果表明:大气CO2浓度升高使绿豆叶、茎、荚、根、地上部分生物量、总生物量及根冠比增加。各发育期地上部分含N量下降10.39%～21.06%,含C量增加0.41%～1.13%,C/N增加12.23%～26.68%;籽粒中N、C含量及C/N无显著变化。植株地上部分吸N量和吸C量分别增加1.99%～50.87%和14.43%～92.69%。未来大气CO2浓度升高条件下,绿豆将通过生物量的增加固定更多的C,并增加对N素的吸收,未来的绿豆生产应考虑增加土壤的施肥水平以保证其养分供应。
