It is important to understand the effects of demineralization on the reactivity of coal pyrolysis for demineralization coal in OCCSS systems.The molecular dynamics of the pyrolysis of ZD-R and ZD-D was investigated us...It is important to understand the effects of demineralization on the reactivity of coal pyrolysis for demineralization coal in OCCSS systems.The molecular dynamics of the pyrolysis of ZD-R and ZD-D was investigated using the ReaxFF MD method.It is indicated that the pyrolysis reactivity of ZD-D is enhanced.Acid demineralization treatment helps to enhance the cross-linking reaction of light tar C5-14 molecules in the main pyrolysis stage,generating light tar fragments with higher molecular mass.In the polycondensation pyrolysis stage,the acid demineralization treatment promotes the polycondensation reaction at high temperatures.The generation of H2 in ZD-R pyrolysis is primarily attributed to the N-H bond breaking in pyrrole at low temperatures.At high temperatures,it is predominantly associated with the hydrogen abstraction reaction between carboxyl functional groups and the dehydrogenation reaction of hydrogen bond breaking in the aliphatic hydrocarbon structures.H2O is primarily attributed to the reaction of the hydroxyl group on the carboxyl group.CO_(2) is always related to the carboxyl group.CO is mainly related to the reduction reaction of carbonyl group,carboxyl group,and CO_(2).During the initial pyrolysis stage of ZD-D after acid demineralization treatment,the hydrogen abstraction reaction of the carboxyl functional group and the generation of CO molecules by the methoxy group are enhanced.The generation of H2 by the aliphatic structure is enhanced in the main pyrolysis stage.The ring-opening reaction of the phenoxy group to generate CO in the polycondensation pyrolysis stage is also facilitated.展开更多
目的:探讨基于T2WI和DWI影像组学在术前无创预测垂体腺瘤质地中的应用价值。方法:回顾性分析经病理证实为垂体腺瘤的108例患者临床及术前MRI资料,术中2名神经外科医生评估肿瘤质地,将其分为质软组和质硬组。按7∶3随机分为训练组和验证...目的:探讨基于T2WI和DWI影像组学在术前无创预测垂体腺瘤质地中的应用价值。方法:回顾性分析经病理证实为垂体腺瘤的108例患者临床及术前MRI资料,术中2名神经外科医生评估肿瘤质地,将其分为质软组和质硬组。按7∶3随机分为训练组和验证组,在T2WI和DWI图像上手动勾画肿瘤实质区的体积作为感兴趣区容积(volume of interest,VOI),用FeAture Explorer软件提取特征,采用无监督特征选择(unsupervised feature selection,UFS)进行特征筛选,采用支持向量机(support vector machine,SVM)构建影像组学模型。通过受试者工作特征曲线下面积(area under curve,AUC)及校准曲线评估模型的效能。结果:在联合T2WI和DWI影像组学模型中,训练组预测垂体腺瘤质地的AUC为0.89,验证组的AUC为0.80。校准曲线显示模型预测值与实际值一致性较好。结论:联合T2WI和DWI影像组学模型具有较好的诊断效能,有助于术前预测垂体腺瘤的质地。展开更多
A differential game guidance scheme with obstacle avoidance,based on the formulation of a combined linear quadratic and norm-bounded differential game,is designed for a three-player engagement scenario,which includes ...A differential game guidance scheme with obstacle avoidance,based on the formulation of a combined linear quadratic and norm-bounded differential game,is designed for a three-player engagement scenario,which includes a pursuer,an interceptor,and an evader.The confrontation between the players is divided into four phases(P1-P4)by introducing the switching time,and proposing different guidance strategies according to the phase where the static obstacle is located:the linear quadratic game method is employed to devise the guidance scheme for the energy optimization when the obstacle is located in the P1 and P3 stages;the norm-bounded differential game guidance strategy is presented to satisfy the acceleration constraint under the circumstance that the obstacle is located in the P2 and P4 phases.Furthermore,the radii of the static obstacle and the interceptor are taken as the design parameters to derive the combined guidance strategy through the dead-zone function,which guarantees that the pursuer avoids the static obstacle,and the interceptor,and attacks the evader.Finally,the nonlinear numerical simulations verify the performance of the game guidance strategy.展开更多
The large-range uncertainties of specific impulse,mass flow per second,aerodynamic coefficients and atmospheric density during rapid turning in solid launch vehicles(SLVs) ascending leads to the deviation of the actua...The large-range uncertainties of specific impulse,mass flow per second,aerodynamic coefficients and atmospheric density during rapid turning in solid launch vehicles(SLVs) ascending leads to the deviation of the actual trajectory from the reference one.One of the traditional trajectory tracking methods is to observe the uncertainties by Extended State Observer(ESO) and then modify the control commands.However,ESO cannot accurately estimate the uncertainties when the uncertainty ranges are large,which reduces the guidance accuracy.This paper introduces differential inclusion(DI) and designs a controller to solve the large-range parameter uncertainties problem.When above uncertainties have large ranges,it can be combined with the ascent dynamic equation and described as a DI system in the mathematical form of a set.If the DI system is stabilized,all the subsets are stabilized.Different from the traditional controllers,the parameters of the designed controller are calculated by the uncertain boundaries.Therefore,the controller can solve the problem of large-range parameter uncertainties of in ascending.Firstly,the ascent deviation system is obtained by linearization along the reference trajectory.The trajectory tracking system with engine parameters and aerodynamic uncertainties is described as an ascent DI system with respect to state deviation,which is called DI system.A DI adaptive saturation tracking controller(DIAST) is proposed to stabilize the DI system.Secondly,an improved barrier Lyapunov function(named time-varying tangent-log barrier Lyapunov function) is proposed to constrain the state deviations.Compared with traditional barrier Lyapunov function,it can dynamically adjust the boundary of deviation convergence,which improve the convergence rate and accuracy of altitude,velocity and LTIA deviation.In addition,the correction amplitudes of angle of attack(AOA) and angle of sideslip(AOS) need to be limited in order to guarantee that the overload constraint is not violated during actual flight.In this paper,a fixed time adaptive saturation compensation auxiliary system is designed to shorten the saturation time and accelerate the convergence rate,which eliminates the adverse effects caused by the saturation.Finally,it is proved that the state deviations are ultimately uniformly bounded under the action of DIAST controller.Simulation results show that the DI ascent tracking system is stabilized within the given uncertainty boundary values.The feasible bounds of uncertainty is broadened compared with Integrated Guidance and Control algorithm.Compared with Robust Gain-Scheduling Control method,the robustness to the engine parameters are greatly improved and the control variable is smoother.展开更多
文摘It is important to understand the effects of demineralization on the reactivity of coal pyrolysis for demineralization coal in OCCSS systems.The molecular dynamics of the pyrolysis of ZD-R and ZD-D was investigated using the ReaxFF MD method.It is indicated that the pyrolysis reactivity of ZD-D is enhanced.Acid demineralization treatment helps to enhance the cross-linking reaction of light tar C5-14 molecules in the main pyrolysis stage,generating light tar fragments with higher molecular mass.In the polycondensation pyrolysis stage,the acid demineralization treatment promotes the polycondensation reaction at high temperatures.The generation of H2 in ZD-R pyrolysis is primarily attributed to the N-H bond breaking in pyrrole at low temperatures.At high temperatures,it is predominantly associated with the hydrogen abstraction reaction between carboxyl functional groups and the dehydrogenation reaction of hydrogen bond breaking in the aliphatic hydrocarbon structures.H2O is primarily attributed to the reaction of the hydroxyl group on the carboxyl group.CO_(2) is always related to the carboxyl group.CO is mainly related to the reduction reaction of carbonyl group,carboxyl group,and CO_(2).During the initial pyrolysis stage of ZD-D after acid demineralization treatment,the hydrogen abstraction reaction of the carboxyl functional group and the generation of CO molecules by the methoxy group are enhanced.The generation of H2 by the aliphatic structure is enhanced in the main pyrolysis stage.The ring-opening reaction of the phenoxy group to generate CO in the polycondensation pyrolysis stage is also facilitated.
文摘目的:探讨基于T2WI和DWI影像组学在术前无创预测垂体腺瘤质地中的应用价值。方法:回顾性分析经病理证实为垂体腺瘤的108例患者临床及术前MRI资料,术中2名神经外科医生评估肿瘤质地,将其分为质软组和质硬组。按7∶3随机分为训练组和验证组,在T2WI和DWI图像上手动勾画肿瘤实质区的体积作为感兴趣区容积(volume of interest,VOI),用FeAture Explorer软件提取特征,采用无监督特征选择(unsupervised feature selection,UFS)进行特征筛选,采用支持向量机(support vector machine,SVM)构建影像组学模型。通过受试者工作特征曲线下面积(area under curve,AUC)及校准曲线评估模型的效能。结果:在联合T2WI和DWI影像组学模型中,训练组预测垂体腺瘤质地的AUC为0.89,验证组的AUC为0.80。校准曲线显示模型预测值与实际值一致性较好。结论:联合T2WI和DWI影像组学模型具有较好的诊断效能,有助于术前预测垂体腺瘤的质地。
基金supported by National Natural Science Foundation(NNSF)of China under(Grant No.62273119)。
文摘A differential game guidance scheme with obstacle avoidance,based on the formulation of a combined linear quadratic and norm-bounded differential game,is designed for a three-player engagement scenario,which includes a pursuer,an interceptor,and an evader.The confrontation between the players is divided into four phases(P1-P4)by introducing the switching time,and proposing different guidance strategies according to the phase where the static obstacle is located:the linear quadratic game method is employed to devise the guidance scheme for the energy optimization when the obstacle is located in the P1 and P3 stages;the norm-bounded differential game guidance strategy is presented to satisfy the acceleration constraint under the circumstance that the obstacle is located in the P2 and P4 phases.Furthermore,the radii of the static obstacle and the interceptor are taken as the design parameters to derive the combined guidance strategy through the dead-zone function,which guarantees that the pursuer avoids the static obstacle,and the interceptor,and attacks the evader.Finally,the nonlinear numerical simulations verify the performance of the game guidance strategy.
基金supported by the National Natural Science Foundation of China (Grant Nos.61627810, 61790562 and 61403096)。
文摘The large-range uncertainties of specific impulse,mass flow per second,aerodynamic coefficients and atmospheric density during rapid turning in solid launch vehicles(SLVs) ascending leads to the deviation of the actual trajectory from the reference one.One of the traditional trajectory tracking methods is to observe the uncertainties by Extended State Observer(ESO) and then modify the control commands.However,ESO cannot accurately estimate the uncertainties when the uncertainty ranges are large,which reduces the guidance accuracy.This paper introduces differential inclusion(DI) and designs a controller to solve the large-range parameter uncertainties problem.When above uncertainties have large ranges,it can be combined with the ascent dynamic equation and described as a DI system in the mathematical form of a set.If the DI system is stabilized,all the subsets are stabilized.Different from the traditional controllers,the parameters of the designed controller are calculated by the uncertain boundaries.Therefore,the controller can solve the problem of large-range parameter uncertainties of in ascending.Firstly,the ascent deviation system is obtained by linearization along the reference trajectory.The trajectory tracking system with engine parameters and aerodynamic uncertainties is described as an ascent DI system with respect to state deviation,which is called DI system.A DI adaptive saturation tracking controller(DIAST) is proposed to stabilize the DI system.Secondly,an improved barrier Lyapunov function(named time-varying tangent-log barrier Lyapunov function) is proposed to constrain the state deviations.Compared with traditional barrier Lyapunov function,it can dynamically adjust the boundary of deviation convergence,which improve the convergence rate and accuracy of altitude,velocity and LTIA deviation.In addition,the correction amplitudes of angle of attack(AOA) and angle of sideslip(AOS) need to be limited in order to guarantee that the overload constraint is not violated during actual flight.In this paper,a fixed time adaptive saturation compensation auxiliary system is designed to shorten the saturation time and accelerate the convergence rate,which eliminates the adverse effects caused by the saturation.Finally,it is proved that the state deviations are ultimately uniformly bounded under the action of DIAST controller.Simulation results show that the DI ascent tracking system is stabilized within the given uncertainty boundary values.The feasible bounds of uncertainty is broadened compared with Integrated Guidance and Control algorithm.Compared with Robust Gain-Scheduling Control method,the robustness to the engine parameters are greatly improved and the control variable is smoother.
