摘要
用化学还原法制备了Ni B非晶态合金催化剂 ,并将其用于 4种卤代硝基苯的液相加氢反应 .采用X射线衍射和透射电子显微镜研究了催化剂的非晶性质 .在 373K下处理 2h后催化剂保持非晶态结构 ,在 773K下处理 2h后催化剂完全晶化 .讨论了Ni B非晶态合金催化剂的催化性能与其结构之间的关系 ,并与其它Ni基催化剂进行了比较 .Ni B非晶态合金催化剂不仅具有较高的催化活性 ,而且对卤代芳胺的选择性较高 ,脱卤率小于 4 % ,优于其它Ni基催化剂 .
The Ni-B amorphous alloy catalyst prepared by reduction of nickel nitrate with a potassium borohydride aqueous solution was employed in the liquid-phase hydrogenation of halogenated nitrobenzene. When the Ni-B amorphous alloy was treated at 373 K, no significant crystallization was observed, but it crystallized at 773 K. The relationship between the catalytic selectivity and the nature of the active sites was discussed based on XRD and TEM characterizations. The higher activity and better selectivity of the amorphous Ni-B catalyst could be attributed to the high dispersion of the Ni active sites and was closely related to both the structural and electronic effects of the active sites. In comparison with other Ni-based catalysts, the Ni-B amorphous alloy catalyst exhibited higher activity and better selectivity for halogenated aniline. The dehalogenation was less than 4%.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2004年第5期369-372,共4页
基金
国家自然科学基金 (2 0 2 760 71)
浙江省重大自然科学基金 (ZE0 10 2 )
关键词
镍
硼
非晶态合金
卤代硝基苯
催化加氢
卤代芳胺
nickel, boron, amorphous alloy, halogenated nitrobenzene, catalytic hydrogenation, halogenated aniline
