摘要
本文通过WAXD和DSC等方法研究了γ-辐照尼龙1010聚集态结构的变化,结晶损伤和无定形化的过程。这些过程和结晶与非晶界面原子参与化学反应密切相关,结晶损伤从结晶表面开始,随着辐照剂量增加逐渐向结晶内伸展,直到完全无定形化。
The effect of gamma-irradiation on the state of aggregation of nylon 1010 was studied by using WAXD and DSC techniques. The results showed that the crystal damage and amorphotization induced by gamma-irradiation are closely related to the chemical reaction of atoms on the interface between crystalline and non-crystalline region of the polymer. The damaging started from the surface of the crystal and proceeded gradually into the crystal, which became completely amorphous when radiation dose was extremely high.
出处
《应用化学》
CAS
CSCD
北大核心
1992年第5期21-24,共4页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金
关键词
尼龙1010
结晶聚合物
辐射效应
Nylon 1010, gamma-ray irradiatiom, aggregated state, radiation crosslinking, WAXD, DSC