摘要
By directly introducing Ni–B into NaAlH4 system using a facile two-step synthesis method, the effects of Ni–B on NaAlH4 were systematically investigated. NaAlH4 can be completely formed after 30 h milling under 1 MPa hydrogen pressure. In addition, the dehydrogenation kinetics of as-prepared NaAlH4 after different milling times were investigated. As the dehydrogenation temperature rises,both the hydrogen desorption capacity and dehydrogenation rate quickly increase. The apparent activation energy E a for Ni–B-doped NaAlH4 is calculated to be 61.91 k J mol-1 for the first dehydrogenation step. More importantly, the dehydrogenation temperature of as-prepared NaAlH4 nanocrystalline can be reduced to about 100 °C.
By directly introducing Ni–B into NaAlH4 system using a facile two-step synthesis method, the effects of Ni–B on NaAlH4 were systematically investigated. NaAlH4 can be completely formed after 30 h milling under 1 MPa hydrogen pressure. In addition, the dehydrogenation kinetics of as-prepared NaAlH4 after different milling times were investigated. As the dehydrogenation temperature rises,both the hydrogen desorption capacity and dehydrogenation rate quickly increase. The apparent activation energy E a for Ni–B-doped NaAlH4 is calculated to be 61.91 k J mol-1 for the first dehydrogenation step. More importantly, the dehydrogenation temperature of as-prepared NaAlH4 nanocrystalline can be reduced to about 100 °C.
基金
financially supported by the Major State Basic Research Development Program of China (Nos. 2010CB631303, and 2012AA051901)
the National Natural Science Foundation of China (Nos. 51071087, and 51171083)
the Program for Changjiang Scholars and Innovative Research Team (No. IRT0927)
the Research Fund for the Doctoral Program of Higher Education of China (No. 20120031110001)
the Natural Science Foundation of Tianjin (No. 11JCYBJC07700)
