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异氰酸酯改性不饱和聚酯的合成及玻璃纤维增强轻质光伏板的制备及性能研究

Synthesis of isocyanate modified unsaturated polyester and preparation and performance study of lightweight photovoltaic panels with glass fiber reinforcement
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摘要 聚酯树脂是热固性树脂在工业中应用最广泛的品种之一,使用异氰酸酯对其进行嵌段改性可以解决普通聚酯树脂固化后脆性大、收缩率高、耐冲击性差及力学性能差等缺点。本文设计了一系列不同的聚酯与异氰酸酯改性,并将其制备成预浸料作为光伏板基板。通过性能表征可知,使用异氰酸酯改性树脂制备的玻璃纤维增强光伏板具有轻质、机械强度高、光透过率高、水汽阻隔效果好、耐黄变、层间不易分层、可靠性佳等特点,其性能远优于普通光伏板性能。 Polyester is not only one of the most widely used varieties of thermosetting resin in the industry,but also the first of the three major matrix resin of composite materials.The block modification of isocyanate can solve the disadvantages of large brittleness,high shrinkage rate,poor impact resistance and poor mechanical properties of ordinary polyester resin after curing.This paper designed a series of different polyester and isocyanate modification,and prepared into prepreg as photovoltaic panel substrate.Through performance characterization,the photovoltaic panel modified by isocyanate has the characteristics of light weight,high mechanical strength,high light transmittance,good water vapor barrier effect,yellowing resistance,not easy stratification between layers,good reliability and so on.The performance is far better than that of ordinary photovoltaic panels.
作者 钱永嘉 蒋红娟 谢耀邦 李鹏环 QIAN Yongjia;JIANG Hongjuan;XIE Yaobang;LI Penghuan(Changzhou Huake Polymers Co.,Ltd.,Changzhou 213000,China)
出处 《复合材料科学与工程》 北大核心 2024年第S1期23-29,共7页 Composites Science and Engineering
关键词 聚酯 预浸料 聚氨酯 嵌段共聚 光伏板 复合材料 polyester prepreg polyurethane block copolymerization photovoltaic panels composites
作者简介 钱永嘉(1971—),男,学士,工程师,研究方向为聚合物基复合材料;通讯作者:蒋红娟(1988—),女,博士,高级工程师,硕士生导师,研究方向为聚合物合成方法学及聚合物基复合材料,jianghongjuan@126.com。
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