摘要
As the climate crisis continues to escalate, there has been a growing emphasis on the development of electrode materials that are environmentally friendly and sustainable. Biomolecules, such as proteins,peptides, and amino acids, have emerged as promising alternatives to metal oxide and metal hydroxide-based energy storage systems. These biomolecules offer several advantages, such as high safety, non-toxicity, abundant raw material sources, and ease of device fabrication. In this review, we highlighted the recent advancements in amino acid, peptide, and protein-based materials for lithiumion batteries, supercapacitors, and fuel cells. We delve into the synthetic strategies employed and their impact on factors such as active potential window, solubility in the electrolyte, and electrochemical performance. Our focus is on the development, composition, and performance of biomolecules, as well as the various approaches taken for their application in batteries, supercapacitors, and fuel cells. Finally, we discuss key considerations that must be taken into account to promote the design, synthesis and development for future practical applications of lithium-ion batteries, supercapacitors, and fuel cells.
基金
financial support from The Director, CSIR-IICT (MS No. IICT/Pubs./2024/043) Hyderabad, India
University Grant Commission (UGC) Faculty Research Program, New Delhi, India (F.4-5(50-FRP) (IV-Cycle)/2017(BSR)) for an award of Professorship。
作者简介
Corresponding authors:Sidhanath V.Bhosale,is a native of Indral,India born in the year 1973.He received his Bachelor degree from Maharashtra Udaygiri Mahavidylay,Udgir[Marathwada University,Aurangabad]in the year 1993 and M.Sc.,in chemistry from Yeshwant Mahavidyalaya,Nanded[Dr.B.A.M.U.Aurangabad],in the year 1995.Dr.Bhosale then worked as Lecturer at S.R T.M.U.Nanded(1995-1998)and K.E.S.Anandibai Pradhan Science College,Nagothane,Raigad(2000-2002)before moving to the Freie Universitat,Berlin,Germany,where he received his doctoral degree[Dr.rer.nat.]in Supramolecular Chemistry under the supervision of Professor J.H.Fuhrhop in 2005.Dr.Bhosale then moved to the University of Geneva,Switzerland,for a postdoctoral fellowship[2006-2007]under the supervision of Dr.Kelly Velonia.Since 2007-2011 he has worked as Reader then Associate Professor at North Maharashtra University,Jalgaon.Currently he is working at the CSIR-Indian Institute of Chemical Technology,Hyderabad as Senior Principal Scientist in Poly-mers and Functional Materials Division.His research interest is in the field of organic and bio-organic supramolecular chemistry,supramolecular polymer chemistry,organic functional materials and chemistry ofπ-conjugated phospho-nate systems.E-mail addresses:bhosale@ict.res.in;Corresponding authors:Sheshanath V.Bhosale has received his PhD in supramolecular chemistry from the Freie University Berlin,Germany,under the supervision of Prof.J.H.Fuhrhop in 2004.Dr.Bhosale pursued his post-doctoral studies with Prof.S.Matile at the University of Geneva,Switzerland,funded by a fellowship by the Roche Foundation.After his post-doc he went to Australia,and has been an ARC-APD fellow researcher for five years at Monash University.He has also worked at RMIT University,Melbourne for 6 years as with an ARC-Future Fellowship.Currently,Prof.Bhosale is working at the School of Chemical Sciences,Central University of Karnataka,Kalaburagi,India as a UGC-FRP Professor,His research interest in design and synthesis of biomaterials andπ-functional materials,especially simall molecules for applications in sensing and supramolecular chemistry..E-mail addresses:bsheshanath@cuk.ac.in;Madan R.Biradar obtained his Master of Science degree from Mumbai University,India in 2015,and further pursued his academic journey by earning a PhD in Chemical Science from CSIR-Indian Institute of Chemical Technology,Hyderabad,India in 2023.His pioneering work focuses on advancing redox active small organic molecules and photopolymers for high-performance supercapacitor and lithium-ion battery applications.He is currently a distinguished postdoctoral Associate at Cornell University in the United States.His research is dedicated to the innovative development and applica-tion of redox and photo polymers for cutting edge energy storage solutions.contributed equally to this work;Harshad A.Mirgane was born in Barshi,Solapur,India.He completed his bachelor degree from Rajaram College Kolhapur and masters in organic chemistry from Vive-kananda College,Kolhapur,India.He qualified various competitive exams such as IIT-JAM,MH-SET,GATE.Currently he is pursuing Ph.D.under the supervision of Prof.S.V.Bhosale at School of Chemical Sciences,Central University of Karnataka,Kalaburagi,India.His research interest is in the synthesis of organic molecules for optoelectronic and sensing applications.contributed equally to this work.
