摘要
催化剂的亲疏水性是影响氧还原反应(Oxyen Reduction Reation,ORR)性能的关键因素之一。本文综述了亲疏水调控策略在提高催化剂性能方面的应用,包括杂原子掺杂、结构设计、表面改性等方法。特别强调了超亲水和超疏水表面在促进氧气传输、增加活性位点和改善三相接触界面方面的作用。为设计高效、稳定的催化剂提供了理论基础和实践指导。
The hydrophilicity of catalyst is one of the key factors affecting the performance of oxygen reduction reaction(ORR).This paper reviews the application of hydrophilic and hydrophobic regulation strategies in improving catalyst performance,including heteroatom doping,structure design,surface modification and so on.In particular,the role of superhydrophilic and superhydrophobic surfaces in promoting oxygen transport,increasing the active site and improving the three-phase contact interface is emphasized.It provides theoretical basis and practical guidance for designing efficient and stable catalysts.
作者
周冰洁
尹硕尧
祝伟康
张灵睿
邵元凯
李振国
Zhou Bingjie;Yin Shuoyao;Zhu Weikang;Zhang Lingrui;Shao Yuankai;Li Zhenguo(CATARC Automobile Inspection Center(Tianjin)Co.,Ltd.,Tianjin,300300;National Engineering Laboratory for Mobile Source Emission Control Technology,China Automotive Technology&Research Center Co.,Ltd.,Tianjin,300300;Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources,School of Materials Science and Technology,China University of Geosciences,Beijing,100083)
出处
《当代化工研究》
CAS
2024年第15期136-138,共3页
Modern Chemical Research
基金
中汽研汽车检验中心(天津)有限公司培育类项目“燃料电池水淹失效机制与低贵金属、高抗水淹催化剂关键技术研究”(项目编号:TJKY2425009)
中国汽车技术研究中心有限公司指南类项目“燃料电池系统失效与安全定量评估技术研究”(项目编号:23243404)。
关键词
催化剂
氧还原
亲水
疏水
catalyst
oxygen reduction
hydrophilic
hydrophobic
作者简介
周冰洁(1990-),女,汉族,博士,高级工程师,研究方向:燃料电池催化材料;通信作者:李振国(1983-),男,汉族,博士,高级工程师,研究方向:节能减排。