摘要
TiO_(2)由于比表面积大、化学性质稳定、具有较高光催化活性等优点,在环境治理保护、光催化降解污染物等方面广泛应用。但其禁带宽度较大,只能吸收紫外光,且光生电子-空穴对再复合率较高,使其对太阳光的利用率大大降低,从而限制了其大规模的工业化应用。因此,如何进一步提高TiO_(2)半导体材料的光催化效果以及对太阳光的利用率备受研究者关注。对TiO_(2)的负载改性方法如非金属元素负载、金属元素负载、半导体复合改性以及染料敏化改性等方面的研究进展进行了综述。
TiO_(2) is widely used in environmental protection and photocatalytic degradation of pollutants due to its large surface area,stable chemical properties and high photocatalytic activity.However,due to its large band gap,it can only absorb ultraviolet light,its utilization rate of sunlight is greatly reduced.In addition,the high recombination rate of photogenerated electron-hole pairs thus limits its large-scale industrial application.Therefore,how to further improve the photocatalytic effect of TiO_(2) and the corresponding utilization rate of sunlight has attracted much attention from researchers.In this paper,the research progress of modification methods for TiO_(2)-based semiconductor materials was reviewed,such as non-metallic element supporting,metal element supporting,semiconductor composite modification and dye sensitization modification.
作者
刘贺津
乔鹏
朴锐
王雪芹
LIU Hejin;QIAO Peng;PIAO Rui;WANG Xueqin(College of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing Heilongjiang163318,China)
出处
《当代化工》
CAS
2024年第4期953-956,996,共5页
Contemporary Chemical Industry
基金
国家自然科学基金青年基金项目(项目编号:21905042)。
作者简介
刘贺津(1998-),男,山东省淄博市人,硕士,研究方向:光催化纳米材料的制备及改性。E-mail:877302858@qq.com;通信作者:王雪芹(1985-),女,教授,博士,研究方向:光催化纳米材料的制备及光解水产氢。E-mail:wangji624@163.com。
