摘要
Two europium-bearing organic frameworks,termed as EuTPO-1 and EuTPO-2(H_(3)TPO=tris(4-carboxylphenyI)-phosphineoxide),are reported in this work.A series of characterizations of EuTPO-1and EuTPO-2,such as X-ray crystallography and photoluminescence spectroscopy,was performed to expatiate their structure and physicochemical properties.Both of them are constructed by dimers of the europium-oxygen subunit of [Eu_(2)O_(16)] and TPO molecule.Benefiting from high X-ray stopping attenuation and excellent luminescence efficiency,they emit sufficient luminescence when irradiated with Xrays.Meanwhile,they possess stable light outputs when exposed to high humidities and strong radiation dose,outperforming the commercial scintillator CsI:Tl.This result paves the way for developing new scintillator and enriches the compound of europium-bearing organic framework with X-ray scintillating luminescence.
基金
Project supported by the National Key R&D Program of China(2021YFB3200400)。
作者简介
Corresponding author:Shu'ao Wang,E-mail address:shuaowang@suda.edu.cn;Yugang Zhang,contributed equally to this work;Lanhua Chen,contributed equally to this work。
