摘要
Asymmetric catalysis has proven remarkably successful in achieving enantioselective control during the construction of new stereogenic centers.However,the challenge of achieving chiral enrichment at pre-existing stereogenic centers,without introducing additional molecular variations,remains a rare and intriguing pursuit known as asymmetric stereochemical editing[1–3].
作者
许言
董广彬
Yan Xu;Guangbin Dong(Beijing National Laboratory for Molecular Sciences(BNLMS),Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China;Department of Chemistry,University of Chicago,Chicago IL 60637,USA)
作者简介
Corresponding authors:Yan Xu received his B.S.degree from Peking University in 2013 and his Ph.D.degree in Chemistry from the University of Chicago with Prof.Guangbin Dong in 2018.After three years of postdoctoral training with Prof.Robert H.Grubbs at California Institution of Technology,he joined the faculty of Peking University as an Assistant Professor in 2021.His current research interest includes new strategies for selective C-H transformations,new coupling reactions using common functional groups,and metathesis polymerization driven by catalyst development.E-mail addresses:yanx@pku.edu.cn;Corresponding authors:Guangbin Dong received his B.S.degree from Peking University in 2003 and his Ph.D.degree in Chemistry from Stanford University with Prof.Barry M.Trost in 2009.After two years of postdoctoral training with Prof.Robert H.Grubbs at California Institution of Technology,he joined the faculty of the University of Texas at Austin in 2011.In 2016,he moved to the University of Chicago as a Professor of Chemistry and now is the Welden G.Brown Professor of Chemisry.His current research interest includes transition-metal-catalyzed C-H and C-C bonds activation,total synthesis of bioactive natural products,boron chemistry,and development of new materials.E-mail addresses:gbdong@uchicago.edu。
