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不同生长调节剂下Cu_(3)(BTC)_(2)的合成与表征

Synthesis and Characterization of Cu_(3)(BTC)_(2)with Different Growth Regulators
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摘要 以硝酸铜(Cu(NO_(3))_(2))为金属源,1,3,5-苯三甲酸(H_(3)BTC)为有机配位体,利用溶剂热合成法制备了金属有机骨架材料Cu_(3)(BTC)_(2)。在三种不同生长调节剂甲酸、乙酸、正丁醇下分别制备得到了金属有机骨架目标化合物。采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、傅立叶变换红外吸收光谱仪(FTIR)等测试手段对所制备样品的微观表面形貌、晶型结构及表面性质等进行了表征,最后对实验测试结果进行了总结分析。 The metal-organic framework material Cu_(3)(BTC)_(2) was prepared by solvothermal method with copper nitrate(Cu_(3)(BTC)_(2))as metal source and 1,3,5-benzenetricarboxylic acid(H_(3)BTC)as organic ligand.The metal-organic frame⁃work target compounds were synthesized using formic acid,acetic acid and n-butanol as different growth regulators,re⁃spectively.Scanning electron microscope(SEM),X-ray diffractometer(XRD)and Fourier transform infrared absorption spectrometer(FTIR)were employed to investigate the micro surface morphology,crystal structure and surface properties of the samples,respectively.Finally,the experimental results were summarized and analyzed.
作者 程宇 邓倩 冯建华 王家琪 CHENG Yu;DENG Qian;FENG Jian-hua;WANG Jia-qi(College of Material and Chemical Engineering,Chuzhou University,Chuzhou 239000,China;Anhui Haihui Chemical Co.Ltd.,Chuzhou 239000,China)
出处 《安徽化工》 CAS 2023年第4期44-48,共5页 Anhui Chemical Industry
基金 滁州学院2022年大学生创新训练计划项目(2022CXXL087) 滁州学院-安徽省海徽化工有限公司横向科研项目(HX2022097) 安徽省示范基层教学组织项目(2020SJSFJXZZ308) 安徽省传统专业改造提升项目(2021zygzts043)。
关键词 生长调节剂 Cu3(BTC)2 溶剂热合成法 金属有机框架 growth regulator Cu_(3)(BTC)_(2) solvothermal synthesis metal-organic framework
作者简介 程宇(2001-),女,本科生;通讯联系人:冯建华,男,博士,副教授,研究方向:膜法水处理,jhfeng920@126.com。
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