摘要
与锂离子电池相比,可充镁离子电池因能量密度高、价格低廉,使用及操作安全以及环境友好等性能而得到了广泛关注,可充镁离子电池在大负荷储能方面具有十分广泛的用途和良好的发展前景。目前,可充镁离子电池的电解液与电极材料的相互兼容性还没有达到较为理想的状态,因此,开发高稳定正极材料和宽电压窗口及无钝化电解质是促进可充镁离子电池产业化应用的关键。该文归纳分析了国内外可充镁离子电池的研究发展现状,详细综述了目前两大研究热点正极材料和电解质,对存在的问题和发展方向进行了总结和展望。
Compared with lithium-ion batteries,rechargeable magnesium-ion batteries have captured wide attention due to their good merits of high energy density,low price,highly safe usage and operation,and environmental friendliness.Rechargeable magnesium-ion batteries are very promising in the application of large load energy storage.However,the compatibility between electrolytes and electrode materials of rechargeable magnesium-ion batteries has not reached a relatively ideal state.Therefore,the development of high stable cathode materials,wide voltage window and non-passivating electrolytes is the key to promote the industrial application of rechargeable magnesium-ion batteries.Herein,the research status at home and abroad about rechargeable magnesium-ion batteries were reviewed.The research progress on the main components of the battery system,such as cathode materials and electrolytes,were discussed in detail.In the end,the existing problems and development directions of rechargeable magnesium-ion batteries were summarized and prospected.
作者
丁波
李明珠
宋广生
熊明文
管秀龙
DING Bo;LI Mingzhu;SONG Guangsheng;XIONG Mingwen;GUAN Xiulong(School of Materials and Chemical Engineering,Bengbu University,Bengbu 233000,Anhui,China;Anhui Provincial Engineering Laboratory of Silicon-based Materials,Bengbu University,Bengbu 233000,Anhui,China;School of Materials Science and Engineering,Anhui University of Technology,Maanshan 243000,Anhui,China)
出处
《精细化工》
EI
CAS
CSCD
北大核心
2023年第8期1667-1678,共12页
Fine Chemicals
基金
安徽省重点研发项目(2022a05020040)
国家级科研基金培育项目(2021pyxm02)
安徽省高端人才资助项目(DT18100044)
国家外国专家引进计划项目(G20190219004)
企业横向课题项目(LS0920、LS0921、RD18200058、2019H3-7、2020H3-8、00011029)。
关键词
可充镁离子电池
嵌入型正极材料
转换型正极材料
有机正极材料
液态电解质
固态电解质
rechargeable magnesium-ion batteries
intercalation cathode materials
conversion cathode materials
organic cathode materials
liquid electrolytes
solid electrolytes
作者简介
丁波(1986—),男,博士,E-mail:www024151@163.com。
