摘要
异靛蓝因其良好的平面性以及较强的拉电子能力,一直作为优秀的受体材料在有机光电材料中扮演着重要的角色,对异靛蓝的结构改造也成为了学术界关注的重点.其中,含氮异靛蓝衍生物的合成及其在光电材料中的应用取得了较大的进展,氮原子的引入可进一步调节异靛蓝衍生物推拉电子的能力以及平面性,从而调节其光电性能.本综述总结了近年来含氮的芳杂环异靛蓝衍生物的发展过程以及在光电材料中的应用,以期为功能化共轭分子的设计提供有益的借鉴和指导.
Isoindigo has played an important role in organic optoelectronic materials as an excellent acceptor building block due to its planarity and electron-withdrawing capability.The modification,of isoindigo has also become the focus of academia.Recently,great achievements have been made in the synthesis of nitrogen-containing isoindigo derivatives and their applications as optoelectronic materials.The incorporation of nitrogen atom can further adjust the electron push/pull ability and the planarity of isoindigo derivatives,thereby tune their optoelectronic properties.The development of nitrogen-containing isoindigo derivatives,as well as their applications in optoelectronic materials,which we hope would provide useful information for the design of conjugated optoelectronic materials,is summarized.
作者
罗力铖
李亮
穆有炳
李博文
万晓波
Luo Licheng;Li Liang;Mu Youbing;Li Bowen;Wan Xiaobo(School of Materials and Engineering,Wuhan Institute of Technology,Wuhan 430074;Key Laboratory of Photoelectrochemical Materials and Devices,Ministry of Education,School of Optoelectronic Materials and Technology,Jianghan University,Wuhan 430056)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2022年第7期1960-1973,共14页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.22075105,22102086)
江汉大学启动基金资助项目。
关键词
含氮异靛蓝
有机光电材料
聚合物场效应晶体管
nitrogen-containing isoindigo
organic optoelectronic materials
polymer field effect transistors
作者简介
Corresponding author:万晓波,wanxb@jhun.edu.cn。
