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Self-assembled MoS_(2)/C nanoflowers with expanded interlayer spacing as a high-performance anode for sodium ion batteries

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摘要 Two-dimensional(2D)MoS_(2) nanomaterials have been extensively studied due to their special structure and high theoretical capacity,but it is still a huge challenge to improve its cycle stability and achieve superior fast charge and discharge performance.Herein,a facile one-step hydrothermal method is proposed to synthetize an ordered and self-assembled MoS_(2) nanoflower(MoS_(2)/C NF)with expanded interlayer spacing via embedding a carbon layer into the interlayer.The carbon layer in the MoS_(2) interlayer can speed the transfer of electrons,while the nanoflower structure promotes the ions transport and improves the structural stability during the charging/discharging process.Therefore,MoS_(2)/C NF electrode exhibits exceptional rate performance(318.2 and 302.3 mA·h·g^(-1) at 5.0 and 10.0 A·g^(-1),respectively)and extraordinary cycle durability(98.8%retention after 300 cycles at a current density of 1.0 A·g^(-1)).This work provides a simple and feasible method for constructing high-performance anode composites for sodium ion batteries with excellent cycle durability and fast charge/discharge ability.
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第11期240-246,共7页 中国化学工程学报(英文版)
基金 National Natural Science Foundation of China(51874142) Pearl River S&T Nova Program of Guangzhou(201806010031) the Fundamental Research Funds for the Central Universities(2019JQ09) Guangdong Innovative and Entrepreneurial Research Team Program(2016ZT06N569) Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program(2019TQ05L903) Young Elite Scientists Sponsorship Program by CAST(2019QNRC001).
作者简介 Corresponding author:Xunhui Xiong,E-mail address:esxxiong@scut.edu.cn。
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