摘要
Two-dimensional(2D)MoS_(2) nanomaterials have been extensively studied due to their special structure and high theoretical capacity,but it is still a huge challenge to improve its cycle stability and achieve superior fast charge and discharge performance.Herein,a facile one-step hydrothermal method is proposed to synthetize an ordered and self-assembled MoS_(2) nanoflower(MoS_(2)/C NF)with expanded interlayer spacing via embedding a carbon layer into the interlayer.The carbon layer in the MoS_(2) interlayer can speed the transfer of electrons,while the nanoflower structure promotes the ions transport and improves the structural stability during the charging/discharging process.Therefore,MoS_(2)/C NF electrode exhibits exceptional rate performance(318.2 and 302.3 mA·h·g^(-1) at 5.0 and 10.0 A·g^(-1),respectively)and extraordinary cycle durability(98.8%retention after 300 cycles at a current density of 1.0 A·g^(-1)).This work provides a simple and feasible method for constructing high-performance anode composites for sodium ion batteries with excellent cycle durability and fast charge/discharge ability.
基金
National Natural Science Foundation of China(51874142)
Pearl River S&T Nova Program of Guangzhou(201806010031)
the Fundamental Research Funds for the Central Universities(2019JQ09)
Guangdong Innovative and Entrepreneurial Research Team Program(2016ZT06N569)
Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program(2019TQ05L903)
Young Elite Scientists Sponsorship Program by CAST(2019QNRC001).
作者简介
Corresponding author:Xunhui Xiong,E-mail address:esxxiong@scut.edu.cn。