摘要
Two new boron imidazolate frameworks(BIFs),Zn2[HBH(2-mim)3]2(1,2-PEA)2(EG)2(BIF-120,EG=ethylene glycol)and Zn[BH(2-mim)3](1,2-HPEA)(BIF-121),were successfully synthesized by mixing the KBH(2-mim)3 ligand and the semirigid aromatic dicarboxylate ligand 1,2-benzenediacetic acid(1,2-H2PEA)under solvothermal conditions.In this paper,the two samples were structurally characterized by single-crystal X-ray diffraction and tested by infrared spectroscopy(IR),UV-visible spectroscopy(UV-Vis),thermogravimetric analysis TGA and X-ray powder diffractions.In addition,the solid-state luminescent properties of these crystals were also investigated.
作者
BI Ming-Yue
WEN Yi-Hang
ZHANG Hai-Xia
ZHANG Jian
毕明月;温一航;张海霞;张健(Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Institute of Physical Chemistry,Zhejiang Normal University,Jinhua 321004,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China)
基金
We gratefully acknowledge the National Key Research and Development Program of China(No.2018YFA0208600)。
作者简介
Corresponding author:温一航,E-mail:wyh@zjnu.cn。
