摘要
A benzotriazole-containing derivative was synthesized via the Mannich reaction.The structure was characterized by NMR spectroscopy.By utilizing computational chemistry and molecular simulation,the calculation and mapping of atomic charge and frontier molecular orbitals with complex structure of the borate were carried out.The acid number of BTBE(nitrogen-containing heterocyclic borate)was determined by the standard test method for acid number and the open observation method.The results showed that BTBE had a low initial acid number,because the acid number was changed only after 72 hours of hydrolysis,and it was negative after the hydrolysis reached 120 hours.The extreme-pressure friction resistance of BTBE and other four base oils was also determined.For 5 kinds of base oils,the friction experiment was carried out under a load of 30 kgf,and the BTBE showed a lowest wear scar diameter(0.365 mm)along with a highest maximum non-seizure load.The results showed that the EP friction resistance of BTBE was stronger than that of other four base oils under the same test conditions.The results of hydrolysis performance showed that the synthesized nitrogencontaining heterocyclic borate had a high resistance to hydrolysis,while demonstrating broad application prospects.
作者简介
Corresponding Author:Professor Lyu Ya,Telephone:+86-21-64252968;E-mail:ylv@ecust.edu.cn.
