摘要
CO是一种廉价、丰富且有用的C1分子,将其作为羰基源参与胺氧化羰基化反应是有机化学中一类重要的反应.近年来,采用胺氧化羰基化合成脲类化合物的技术路线备受关注.我们综述了催化剂参与的胺氧化羰基化合成脲类化合物的研究现状,还对胺氧化羰基化反应的发展趋势进行了展望.
CO is a an inexpensive,abundant and useful C1 building block.It is an important transformation in organic chemistry to use CO as a carbonyl source to participate in the oxidation carbonylation of amine.Synthesis of urea and its derivatives by the oxidation carbonylation of amine has attracted much attention in recent year.This review intends to offer a detailed introduction of recent progress on the synthesis of urea by catalytic oxidative carbonylation of amines.Moreover,the development tendency for oxidative carbonylation of amine are also discussed.
作者
曹彦伟
张雪华
何林
Yan-wei;ZHANG Xue-hua;HE Lin(Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China;University of Chinese Academy of Sciences,Beijing 100049,China;School of Chemistry and Environmental Engineering,Yancheng Teachers University,Yancheng 224007,China)
出处
《分子催化》
EI
CAS
CSCD
北大核心
2020年第2期182-192,I0003,共12页
Journal of Molecular Catalysis(China)
基金
国家自然科学基金(91645118,21633013,21773275),江苏省自然科学基金(BK20180249),中国科学院前沿科学重点研究计划(QYZDJ-SSW-SLH051)。
关键词
一氧化碳
胺
氧化羰基化
脲
CO
amine
oxidative carbonylation
urea
作者简介
曹彦伟(1990-),男,博士研究生,E-mail:cyw929@licp.cas.cn;通讯联系人:张雪华,xuehuazhang1984@163.com;通讯联系人:何林,helin@licp.cas.cn。
