摘要
以甲基丙烯酸二甲氨基乙酯为母体、对氯甲基苯乙烯为季铵化试剂,合成了一种具有疏水结构的甲基丙烯酸二甲氨基乙酯型离子液体(DEMA).通过失重实验、电化学分析、原子力显微镜(AFM)、接触角测试和量子化学计算等研究了DEMA在1 mol/L盐酸中对Q235钢的缓蚀性能,并揭示了其在Q235钢表面的吸附行为和吸附机理.失重实验结果表明,DEMA在盐酸中对Q235钢具有优异的缓蚀效果,且在较高温度(60℃)下也能保持高效吸附;电化学实验结果与失重测试结果一致;接触角测试结果表明,DEMA可明显增强Q235钢表面的疏水性;分析热力学参数可知,DEMA在Q235钢表面的吸附为自发、放热过程,符合Langmuir等温式,且以化学吸附为主;量子化学计算结果证实DEMA的结构中包含大量吸附活性位点.
A 2-( dimethylamino) ethyl methacrylate type ionic liquid with hydrophobic structure( DEMA) was prepared from 2-( dimethylamino) ethylmethacrylate and 4-vinylbenzyl chloride. The corrosion inhibitory property of DEMA on Q235 steel in 1 mol/L hydrochloric acid solution and their adsorption behavior on Q235 steel surface were studied by means of mass loss measurement,electrochemical technique,force microscopy( AFM),contact angle measurement and quantum chemical calculation. The mass loss results show that DEMA has good corrosion inhibition effect on Q235 steel in hydrochloric acid,and it can maintain strong adsorption at higher temperature( 60 ℃) . The results of electrochemical tests are consistent with that of mass loss test.Contact angle test results show that DEMA can significantly enhance the hydrophobicity of the surface of Q235 steel. Thermodynamic and activation energy parameters show that the adsorption of DEMA on Q235 steel surface is spontaneous and exothermic,conforming to the Langmuir’s adsorption isotherm and mainly based on chemical adsorption. Quantum chemical calculation results show that the entire structure of DEMA contains a large number of adsorbed active sites. Thermogravimetric analysis( TGA) shows that DEMA has good thermostability. DEMA has the advantages of mild preparation condition,good thermal stability and excellent corrosion inhibition performance,thus it has important industrial application value and theoretical reference. At the same time,the studies also provide a new idea for the structural design of corrosion inhibitor.
作者
董秋辰
张光华
张万斌
张雪
刘晶
DONG Qiuchen;ZHANG Guanghua;ZHANG Wanbin;ZHANG Xue;LIU Jing(Shaanxi Key Laboratory of Chemical Additives for Industry,Shaanxi University of Science and Technology,Xi’an 710021,China;Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology,Shaanxi University of Science and Technology,Xi’an 710021,China)
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2019年第12期2556-2565,共10页
Chemical Journal of Chinese Universities
基金
国家自然科学基金(批准号:31670596)
陕西省教育厅重点实验室科研计划项目(批准号:14JS015)资助~~
关键词
缓蚀剂
离子液体
吸附
量子化学
缓蚀机理
Corrosion inhibitor
Ionic liquid
Adsorption
Quantum chemical
Inhibition mechanism
作者简介
联系人:张光华,男,博士,教授,主要从事精细有机合成及能源化工助剂研究.E-mail:zhanggh@sust.edu.cn。
