摘要
The HY,Hβ,HZSM-5,and SAPO-11 zeolites were investigated in the alkylation reaction of thiophene and olefins.As a result,some sulfur-containing impurities could be converted to higher molecular weight components with their boiling point being in the range of diesel fraction.HZSM-5 had the highest activity and selectivity of desulfurization.At the same time,extensive oligomerization of olefins was not found and coke yield was very low,which could lead to high yield of gasoline products.The main reaction mechanism verifies that the second order alkylation reaction can be carried out on the outer surface and/or pores of the catalyst.The catalytic performance of the HZSM-5 catalyst which is poisoned by 2,4-dimethylquinoline during alkylation to form larger molecules of sulfur compounds is obviously weakened due to the decrease of the acid sites on the outer surface and at the mouth of pores.
The HY, Hβ, HZSM-5, and SAPO-11 zeolites were investigated in the alkylation reaction of thiophene and olefins.As a result, some sulfur-containing impurities could be converted to higher molecular weight components with their boiling point being in the range of diesel fraction. HZSM-5 had the highest activity and selectivity of desulfurization. At the same time, extensive oligomerization of olefins was not found and coke yield was very low, which could lead to high yield of gasoline products. The main reaction mechanism verifies that the second order alkylation reaction can be carried out on the outer surface and/or pores of the catalyst. The catalytic performance of the HZSM-5 catalyst which is poisoned by 2,4-dimethylquinoline during alkylation to form larger molecules of sulfur compounds is obviously weakened due to the decrease of the acid sites on the outer surface and at the mouth of pores.
作者简介
Corresponding Author:Dr.Xu Yun,Telephone:+86-10-82368412;E-mail:xuyun.ripp@sinopec.com.
