摘要
LiNi0.9Co0.15Al0.05O2 （NCA） material is successfully synthesized with a modified co-precipitation method,in which NH3,H2O and EDTA are used as two chelating agents. The obtained LiNi0.9Co0.15Al0.05O2 materialhas well-defined layered structure and uniform element distribution, which reveals an enhanced electro-chemical performance with a capacity retention of 97.9% after 100 cycles at 0.2 C, and reduced thermalrunaway from the isothermal calorimetry test. In situ X-ray diffraction （XRD） was employed to capturethe structural changes during the charge-discharge process. The reversible evolutions of lattice parame-ters （a, b, c, and V） further verify the structural stability.
LiNi0.9Co0.15Al0.05O2 （NCA） material is successfully synthesized with a modified co-precipitation method,in which NH3,H2O and EDTA are used as two chelating agents. The obtained LiNi0.9Co0.15Al0.05O2 materialhas well-defined layered structure and uniform element distribution, which reveals an enhanced electro-chemical performance with a capacity retention of 97.9% after 100 cycles at 0.2 C, and reduced thermalrunaway from the isothermal calorimetry test. In situ X-ray diffraction （XRD） was employed to capturethe structural changes during the charge-discharge process. The reversible evolutions of lattice parame-ters （a, b, c, and V） further verify the structural stability.
基金
partially supported by the National Key Research and Development Program of China (2016YFB0100203)
the National Natural Science Foundation of China (21673116,21633003)
the Natural Science Foundation of Jiangsu Province of China (BK20160068)
PAPD of Jiangsu Higher Education Institutions
作者简介
Corresponding authors at： Center of Energy Storage Materials ＆ Technology, College of Engineering and Applied Sciences, National Laboratory of Solid State Microstructures, and Collaborative Innovation Center of Advanced Microstructure, Nanjing University, Nanjing 210093, Jiangsu, China. E-mail： addresses： pinghe@nju.edu.cn;Corresponding authors at： Center of Energy Storage Materials ＆ Technology, College of Engineering and Applied Sciences, National Laboratory of Solid State Microstructures, and Collaborative Innovation Center of Advanced Microstructure, Nanjing University, Nanjing 210093, Jiangsu, China. E-mail addresses： hszhou@nju.edu.cn
