摘要
以氧化石墨烯为吸附剂,建立一种固相萃取方法,从花旗参茶饮料中萃取氟氯氰菊酯、七氟菊酯、氯戊菊酯、氯菊酯和联苯菊酯5种拟除虫菊酯类农药残留,并通过单因素实验和正交实验对萃取条件进行优化,考察氧化石墨烯用量、洗脱剂种类、洗脱剂体积和萃取时间对萃取效果的影响.结果表明,在最佳萃取条件下,拟除虫菊酯类农药的富集效果较好,氟氯氰菊酯、七氟菊酯、氯戊菊酯、氯菊酯和联苯菊酯的回收率分别为105.98%,65.93%,105.17%,93.69%,89.46%.
Using oxide graphene as sorbent,we established a solid-phase extraction method for the extraction of five pyrethroid pesticide residues of cyfluthrin,tefluthrin,fenvalerate,permethrin and bifenthrin from ginseng beverage.The extraction conditions were optimized by single factor experiment and orthogonal experiment.We investigated the effect of the amount of oxide graphene,the type and volume of eluent and the extraction time on the extraction.The results show that the enrichment effect of pyrethriod pesticide residues is better,the recovery rates of cyfluthrin,tefluthrin,fenvalerate,permethrin and bifenthrin are 105.98%,65.93,105.17%,93.69% and89.46%respectively under the optimal extraction conditions.
作者
张璐
李绪文
王博
杨艳萍
刘佳慧
金永日
时晓磊
ZHANG Lu;LI Xuwen;WANG Bo;YANG Yanping;LIU Jiahui;JIN Yongri;SHI Xiaolei(College of Food Science and Engineering,Jilin University,Changchun 130062,China;College of Chemistry,Jilin University,Changchun 130013,China)
出处
《吉林大学学报（理学版）》
CAS
CSCD
北大核心
2018年第4期1000-1006,共7页
Journal of Jilin University:Science Edition
基金
国家自然科学基金青年科学基金(批准号:31201295)
关键词
氧化石墨烯
饮料
富集
拟除虫菊酯
农药残留
oxide graphene
beverage
enrichment
pyrethriod
pesticide residue
作者简介
张璐（1994-）,女,汉族,硕士研究生,从事天然产物抗过敏的研究,E-mail：zhanglua11@163.com.;通信作者：时晓磊（1982-）,女,汉族,博士,副教授,从事天然产物抗过敏的研究,E-mail：xlshi@jlu.edu.cn.
