摘要
Currently, carbon materials, such as graphene,carbon nanotubes, activated carbon, porous carbon, have been successfully applied in energy storage area by taking advantage of their structural and functional diversity. However, the development of advanced science and technology has spurred demands for green and sustainable energy storage materials.Biomass-derived carbon, as a type of electrode materials, has attracted much attention because of its structural diversities,adjustable physical/chemical properties, environmental friendliness and considerable economic value. Because the nature contributes the biomass with bizarre micro structures,the biomass-derived carbon materials also show naturally structural diversities, such as OD spherical, 1D fibrous, 2D lamellar and 3D spatial structures. In this review, the structure design of biomass-derived carbon materials for energy storage is presented. The effects of structural diversity, porosity and surface heteroatom doping of biomass-derived carbon materials in supercapacitors, lithium-ion batteries and sodium-ion batteries are discussed in detail. In addition, the new trends and challenges in biomass-derived carbon materials have also been proposed for further rational design of biomass-derived carbon materials for energy storage.
目前,碳材料依靠其自身结构和功能的多样性,已成功地应用于能源储存领域.先进科学与技术的发展促使我们对绿色和可持续的储能材料需求越来越迫切,生物质衍生碳因其结构的多样性、可调节的物理/化学性质、环境友好和价格低廉而引起人们的广泛关注.由于自然界赋予生物质奇异的微观结构,导致其衍生碳材料也显示出结构多样性,如零维的球形、一维的纤维、二维的片层和三维的空间结构.本综述介绍了生物质衍生碳材料的结构多样性,多孔特性,表面改性和杂原子掺杂,及其在超级电容器、锂离子电池和钠离子电池中的应用,并提出未来发展的趋势和挑战.
基金
supported by the National Natural Science Foundation of China (51702117,51672055)
Major Research Projects Fund of Jilin Institute of Chemical Technology (2016006)
Natural Science Foundation of Heilongjiang Province of China (E201416)
作者简介
Lili Jiang received her PhD degree in 2016 at the College of Materials Science and Chemical Engineering at Harbin Engineering University. She is now an associate professor at lilin Institute of Chemical Technology. Her current research is focused on the design and synthesis of functional carbonaceous nanomaterials as well as their applications tbr energy conversion and storage devices.;Lizhi Sheng currently is pursuing PhD degree in the College of Materials Science and Chemical Engineering at Harbin Engineering University. His research interests mainly focus on the design and synthesis of functional carbonaceous nanomaterials and their applications for energy storage.;Corresponding author （email： fanzhj666@163.com）.Zhuangjun Fan received his PhD in 2003 at the Institute of Coal Chemistry, Chinese Academy of Sciences. He became full professor at the College of Materials Science and Chemical Engineering in 2006, and now he is the director of tile Institue of Advanced Carbon Based Materials at Harbin Engineering University. His research interests locus on the design and controlled synthesis of carbon nanomaterials such as carbon nanotubes and graphene, and their applications in energy-related areas such as supercapacitors, Li ion batteries and full cells.
