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对位芳纶浆粕形态结构与性能研究 被引量:3

Study on Structure and Performance of Para-aramid Pulps
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摘要 对比分析了喷射纺丝法(jet-spun)和原纤化处理得到的两种对位芳纶浆粕的比表面积、保水值、动态滤水等特性。扫描电子显微镜(SEM)观察发现,喷射纺丝法制备得到的浆粕1呈薄膜状,比表面积为26.365 m^2/g;原纤化处理得到的浆粕2中存在纳米级直径的原纤化纤维细丝,比表面积为15.157 m^2/g。动态滤水曲线表明,浆粕1的滤水速率更慢,对滤水的阻碍作用更大。浆粕1的纸基材料抗张指数为42.3 N·m/g,高于浆粕2的;浆粕1与对位芳纶纤维混合抄造的纸基材料抗张指数为34.0 N·m/g,同样高于浆粕2与对位芳纶纤维混合抄造纸基材料的。 The structure and performance of two kinds of para-aramid pulp were compared. One was obtained by jet-spun process ( pulp 1 ) , the other was fibrillated by mechanical force ( pulp 2). In this paper, specific surface area, water retention value (WRV) and property of dynamic drainage of the para-aramid pulps were studied. The results of scanning electron microscopy ( SEM ) showed that pulp 1 had a flexible sheet structure while pulp 2 contained fibrillated nano-fiber. The specific surface area of pulp 1 was 26. 365 m2/g and pulp 2 was 15. 157 m2/g. The dynamic drainage curve indicated that pulp 1's drainage rate was lower than pulp 2 so that pulp 1 was more difficult to drain water off. The tensile index of paper-based composite made from pulp 1 was 42.3 N·m/g that was higher than pulp 2 ; And the tensile index of paper-based composite of fiber and pulp 1 was 34.0 N·m/g, which was also higher than that made from fiber and pulp 2.
作者 曹雪鸿 王宜 耿浩 胡健 CAO Xue-hong WANG Yi GENG Hao HU Jian(State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou , Guangdong Province, 510640)
出处 《中国造纸》 CAS 北大核心 2017年第2期18-22,共5页 China Pulp & Paper
关键词 对位芳纶浆粕 微观形态 性能 para-aramid pulps microtopography performance
作者简介 曹雪鸿女士,在读硕士研究生;研究方向:合成浆粕结构与性能研究。 通信作者:王宜,副研究员;研究方向:高性能纤维及纸基材料性能研究。
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  • 1Keller T S.Pbysicochemical Aspects of Polymer Surfaces[M].Newyork:Plenum Press,1981.
  • 2Chatzi E G.Characterization of the surface hydrolysis of Kevlar-49 fibers by diffuse reflectance FTIR spectrcscopy[J].Journal of Polymer Sciece:Polymer Physics Edition,1988,26(8):1585.
  • 3Sokolova T S.Hydrolytic stability of poly-p-phenylene terephthalamide in sulfuric acid solutions[J].Fiber chemistry,1976,8(1):45.

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