摘要
以四氢苯酐为起始原料,依次经酯化、酰胺化及氧化开环反应合成了新型烷基酰胺双羧酸盐双子表面活性剂(4),其结构经1H NMR,IR和MS(ESI)表征。通过浊点法测得其Krafft点低于0℃;通过电导率法测得其CMC为3.729×10-3mol·L^(-1);利用滴体积法测得CMC为3.402×10^(-4)mol·L^(-1),γCMC为36.88 m N·m^(-1)。4的起泡性能、乳化性能良好,优于SDS。
A novel dicarboxylic surfactant（4） based on alkyl amide was synthesized by esterifying,amidating and oxidizing,using tetradrophthalic anhydride as the starting material.The structure was characterized by -1H NMR,IR and MS（ESI）.The Krafft point tested by means of cloud point was below 0 ℃.The critical micelle concentration（CMC） tested by conductivity method was 3.729×10^-3mol·L^-1.The CMC and γCMCtested by dripping volume method were 3.402×10^-4mol·L^-1 and 36.88 m N·m^-1,respectively.The results of foam experiment showed that 4 has better foaming capacity than that of SDS.
作者
孙硕
潘忠稳
周杨
张振伟
SUN Shuo PAN Zhong-wen ZHOU Yang ZHANG Zhen-wei(School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China)
出处
《合成化学》
CAS
CSCD
2017年第1期42-46,共5页
Chinese Journal of Synthetic Chemistry
关键词
四氢苯酐
酰胺双羧酸盐
双子表面活性剂
合成
表面性质
tetradrophthalic anhydride
dicarboxylic surfactant
gemini surfactant
synthesis
surface property
作者简介
孙硕（1989-），男，汉族，安徽淮北人，硕士研究生，主要从事表面活性剂的合成及性能研究。E-mail：1162752974@qq.com
通信联系人：潘忠稳，教授级高工，E—mail：ahpzw@163．com
