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Photo-depositing Ru and RuO2 on Anatase TiO2 Nanosheets as Co-catalysts for Photocatalytic O2 Evolution from Water Oxidation 被引量:1

光沉积Ru和RuO2的锐钛矿TiO2纳米片的光解水产氧
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摘要 TiO2 nanosheets mainly exposed (001) facet were prepared through a hydrothermal process with HF as the morphology-directing agent. Ru and RuO2 species were loaded by photo-deposition methods to prepare the photocatalysts. The structural features of the catalysts were characterized by X-ray di raction, transmission electron microscopy, inductively cou-pled plasma atomic emission spectrum, and H2 Temperature-programmed reduction. The photocatalytic property was studied by the O2 evolution from water oxidation, which was examined with respect to the in uences of Ru contents as well as the oxidation and reduction treatments, suggesting the charge separation effect of the Ru species co-catalysts on di erent facets of TiO2 nanosheets. In contrast to Ru/TiO2 and RuO2/TiO2 with the single deposited co-catalyst, the optimized catalyst 0.5%Ru-1.0%RuO2/TiO2 with dual co-catalysts achieved a much improved catalytic performance, in terms of the synergetic effect of dual co-catalysts and the enhanced charge separation effect.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2016年第5期585-590,I0002,共7页 化学物理学报(英文)
关键词 Anatase TiO2 nanosheets Photocatalytic O2 evolution Crystal facet Ru co-catalyst Charge separation 锐钛矿TiO2纳米片 光解水产氧 晶面 Ru助催化剂 电荷分离
分类号 O [理学]
作者简介 Author to whom correspondence should be addressed. E-mail: wangwd@ustc.edu.cn, Tel.: +86-551-63603683
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