摘要
The communication reports an exploratory experimental study on the effects of nitrogen annealing on lithium ion intercalation in nickel-doped lithium trivana- date cathodic electrodes for lithium ion batteries. It shows good rate performance with discharge capacities of 348.6, 252.6, 191.9 and 96.7 mAh g-1 at 0.2, 0.5, 1 and 5 C, respectively. Nitrogen annealing resulted in the formation of parasitic secondary-phase LiVzO5 and appreciably increased tetravalent vanadium ions compensated with oxygen vacancies, which would enhance the electronic conductivity and lithium ion diffusivity and promote the interface interaction and deintercalation process, and thus lead to the enhanced lithium ion intercalation properties. The possible impacts of the parasitic secondary-phase LiV205 on the lithium ion intercalation performance have also been discussed.
The communication reports an exploratory experimental study on the effects of nitrogen annealing on lithium ion intercalation in nickel-doped lithium trivanadate cathodic electrodes for lithium ion batteries. It shows good rate performance with discharge capacities of 348.6,252.6, 191.9 and 96.7 m Ah g^(-1)at 0.2, 0.5, 1 and 5 C,respectively. Nitrogen annealing resulted in the formation of parasitic secondary-phase Li V_2O_5 and appreciably increased tetravalent vanadium ions compensated with oxygen vacancies, which would enhance the electronic conductivity and lithium ion diffusivity and promote the interface interaction and deintercalation process, and thus lead to the enhanced lithium ion intercalation properties.The possible impacts of the parasitic secondary-phase Li V_2O_5 on the lithium ion intercalation performance have also been discussed.
基金
supported by the‘‘Thousands Talents’’Program for a pioneer researcher and his innovative team
China
supported by the National Natural Science Foundation of China(51374029)
the National Science Foundation(NSF
DMR-1505902)
Program for New Century Excellent Talents in University(NCET-13-0668)
Fundamental Research Funds for the Central Universities(FRF-TP-14-008C1)
China Postdoctoral Science Foundation(2015M570988)
作者简介
e-mail： gzcao @u.washington.edu
