摘要
二次谐波线二向色性方法是定量研究气液界面手性的重要光学方法,此方法得到的手性响应既可能来源于界面超分子的电偶极矩的贡献,也可能是电偶极矩和磁偶极矩的共同贡献。分清这两种贡献,是研究界面超分子手性形成机理的前提条件。对两种情况下S偏振的二次谐波强度的偏振公式进行了对比分析和数值模拟,总结了各自的偏振曲线的线型特点,进一步分析了电偶极矩和磁偶极矩的二阶非线性极化率张量分量对手性响应的影响。推导了两种情况下表征界面手性的物理量——手性过量的表达式,分析了电偶极矩和磁偶极矩对手性过量的影响。通过卟啉气液界面手性的实验检测结果,验证了理论分析的正确性,该模拟对实验数据分析有重要意义。
Second harmonic generation（SHG）- linear dichroism（SHG- LD） is an important method for the investigation of monolayer chirality at air/water interface. The chirality SHG response may originate from the contributions of electric dipole transitions or from contributions of both electric dipole transitions and magnetic dipole transitions. The distinction between these two cases is a prerequisite when studying the formation mechanism of the interfacial supramolecular chiraliy. The numerical simulations of the S-polarized SHG intensity as a function of the incident polarization angle are presented and compared for the two cases. The influences on the chirality SHG responses from the second-order nonlinear susceptibility tensors which account for the contributions of electric dipole transitions and magnetic dipole transitions are also analyzed, respectively. In addition, the significance of theoretical simulations to the analysis of experimental data is verified by the SHG- LD experiments on the supramolecular chirality of the porphyrin molecules at air/water interface.
出处
《光学学报》
EI
CAS
CSCD
北大核心
2015年第3期225-233,共9页
Acta Optica Sinica
基金
国家自然科学基金(91027042
21227802)
关键词
非线性光学
手性
二次谐波的线二向色性
电偶极跃迁
磁偶极跃迁
nonlinear optics
chirality
second harmonic generation-linear dichroism
electric dipole transition
magnetic dipole transition
作者简介
王晓宇（1981-），女，博士研究生，主要从事非线性光学方法研究界面分子取向等方面研究。E—mail：reallyxiaoyu@126．com
导师简介：李林（1957-），男，教授，博士生导师，主要从事光学设计与检测等方面研究。E—mail：li_lin@263．net（通信联系人）
