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Synthesis of Gas Transport through Nano Composite Ceramic Membrane for Esterification and Volatile Organic Compound Separations

Synthesis of Gas Transport through Nano Composite Ceramic Membrane for Esterification and Volatile Organic Compound Separations
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摘要 The transport behaviour of carrier gases with inorganic catalytic ceramic membrane used for ethyl lactate production and VOC (volatile organic compound) recovery in the gauge pressure range of 0.10-1.00 bar and temperature range of 333 K was investigated. The gases include Ar (argon), N2 (nitrogen) and CO2 (carbon dioxide). The gas kinetic diameter with respect to permenace was found to occur in the order of At 〉 CO2 〉 N2, which was not in agreement with molecular sieving mechanism of transport after the first dip-coating of the support. However, gas flow rate was found to increase with gauge pressure in the order of Ar 〉 CO2 〉 N2, indicating Knudsen mechanism of transport. The porous ceramic support showed a higher flux indicating Knudsen transport. The surface image of the dip-coated porous ceramic membrane was characterised using SEM (scanning electron microscopy) to determine the surface morphology of the porous support at 333 K.
出处 《Journal of Mechanics Engineering and Automation》 2014年第11期905-913,共9页 机械工程与自动化(英文版)
关键词 Inorganic ceramic membrane PERMEANCE gas flow rate and kinetic diameter 挥发性有机化合物 天然气运输 复合陶瓷膜 多孔陶瓷膜 扫描电子显微镜 气体动力学 分色 合成
作者简介 Edward Gobina, Gas2 chair in Ceramic Membrane Technology, research fields: chemical and process engineering. E-mail: e.gobina@rgu.ac.uk.
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