摘要
A novel bis(8-oxide quinoline)zironium phthalocyanine [(OQ)2 Zr Pc] with two 8-oxide quinolone anions at the same axial positions has been successfully synthesized and its chemical structure has been assigned by the 1 H NMR, MS and two-dimensional correlation infrared(2D-IR) spectroscopy as well as by single-crystal X-ray structural analysis. It possessed a moderately effective nonlinear absorption coefficient βeff of 6.69×10-14cm/GW at 532 nm in DMF solution, implying it is a promising candidate for nonlinear optical materials.
A novel bis(8-oxide quinoline)zironium phthalocyanine [(OQ)2 Zr Pc] with two 8-oxide quinolone anions at the same axial positions has been successfully synthesized and its chemical structure has been assigned by the 1 H NMR, MS and two-dimensional correlation infrared(2D-IR) spectroscopy as well as by single-crystal X-ray structural analysis. It possessed a moderately effective nonlinear absorption coefficient βeff of 6.69×10^(-14) cm/GW at 532 nm in DMF solution, implying it is a promising candidate for nonlinear optical materials.
基金
supported by the Natural Science Foundation of Fujian Province(2018J01431 and 2018J01690)
Research Foundation of Education Bureau of Fujian Province(JT180813)
作者简介
Corresponding author.Prof.Lin Mei-Jin,for the research interests,see homepage:http://supramol.fzu.edu.cn;E-mail.meijin._lin@fzu.edu.cn.
