摘要
锂硫电池的理论能量密度为2600 Wh/kg,是锂离子二次电池的3—5倍,是极具应用前景的电化学储能体系,近年来引起了研究人员的广泛关注。人们在维持电极结构稳定性、提高硫的利用率和加强电池循环寿命等方面开展了大量的研究工作。本文综述了锂硫电池的最新研究进展,从硫正极材料复合改性、不同种类电解质、锂负极保护、电池结构设计等4个方面进行了总结,分析了影响锂硫电池比容量、循环稳定性的主要因素,最后展望了锂硫电池未来的发展趋势。
Lithium-sulfur （Li-S） battery is a promising electrochemical energy storage system that has high theoretical energy density of 2600 Wh·kg^-1, which is 3 to 5 times that of Li-ion batteries. It has attracted more and more attentions in recent years. Great efforts have been made to improve the stability of electrode structure, the utilization efficiency of sulfur in the cathode and the enhancement of cycle life of the battery. In this paper, the recent progress of the lithium-sulfur battery is reviewed from four aspects： modification of sulfur-based composite cathode material, electrolytes, protection of lithium anode and design of lithium-sulfur cell configurations. The main factors on the specific capacity and cycle stability of the lithium-sulfur battery are analyzed. The prospects and development trends on lithium-sulfur battery are also discussed.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2013年第11期1830-1841,共12页
Progress in Chemistry
基金
国家高技术发展计划(863)项目(No.2011AA11A257)资助
关键词
锂硫电池
硫基复合正极
电解质
锂负极
循环寿命
lithium-sulfur battery
sulfur-based composite cathode
electrolytes
lithium anode
cycle life
作者简介
Corresponding author e-mail： puwh@ tsinghua, edu. cn
