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S_t-g-PDMC/PVA共混薄膜的研究 被引量:1

Study on the properties of S_t -g-PDMC / PVA film
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摘要 合成了淀粉-g-聚甲基丙烯酰氧乙基三甲基氯化铵(St-g-PDMC),并与PVA共混,研究了St-g-PDMC/PVA共混比对共混薄膜的力学性能、抗弯曲性、水溶时间及吸湿率的影响,同时验证其对涤/棉纤维粘合性的影响。结果表明,随着PVA含量的增加,共混薄膜的断裂强度降低,伸长率和抗弯曲性能变好,水溶时间和吸湿率变小,对涤/棉纤维的粘合力先增大后减小,在St-g-PDMC/PVA共混比为60∶40时强力最大。 To examine the end-use ability of starch-g-poly (methacryloxyethyltrimethyl ammonium chlo- ride) (St-g-PDMC)/PVA film. Effect of St-g-PDMC/PVA ratio on the film mechanical properties,the time required to break the film in water, bending resistant and hygroscopicity were studied. Meanwhile, effect of St-g-PDMC/PVA ratio on adhesion to polYester/cotton fibers was also studied. The results showed that breaking strength, the time required to break the film in water and hygroscopicity of film were reduced with the increased the content of PVA, and improved the breaking elongation ,bending resistant of film. As the content of PVA increased, the adhesion to the polyester/cotton fibers initially increased and then de- creased, and reached a maximal value when St-e-PDMC/PVA ratio was 60: 40.
出处 《应用化工》 CAS CSCD 2013年第10期1816-1819,共4页 Applied Chemical Industry
基金 教育部生态纺织重点实验室开放基金资助项目(KLET0617)
关键词 阳离子型接枝淀粉 PVA 薄膜 粘合强度 cationically grafted starch PVA film adhesion
作者简介 祝忠秋(1987-),男,江西玉山人,江南大学在读硕士研究生,师从祝志峰教授,从事纺织浆料和高分子化学方面研究。电话:18262299775,E—mail:zhuzhongqiu@126.com
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参考文献14

  • 1Liu C, Shao Y, Jia D M. Chemically modified starch rein- forced natural rubber composites [ J ]. Polymer, 2008,49 : 2176-2181.
  • 2祝忠秋,祝志峰,屈磊.阳离子型接枝淀粉浆料的性能分析[J].棉纺织技术,2013,41(2):1-4. 被引量:3
  • 3曾祥成,刘白玲,李坤福.高速搅拌对淀粉/聚乙烯醇共混物溶液成膜性能的影响[J].高分子学报,1999,9(1):68-73. 被引量:16
  • 4Zhu Z F, Zhuo R X. Controlled release of carboxylic- containing herbicides by starch-g-poly (butyl acrylate ) [ J ]. Journal of Applied Polymer Science, 2001,81 : 1535- 1543.
  • 5Zhu Z F, Qian K. Effects of the molecular structure of pol- yvinyl alcohol on the adhesion to fibre substrates [ J ]. Fi- bres & Textiles in Eastern Europe,2007,15:82-85.
  • 6Block J, Waters Jr O B. Interference of the ammoniun ion in Mohr' s method for the determination of chloride [ J ]. Talanta, 1967,14 : 1130-1131.
  • 7中华人民共和国国家发展和改革委员会.FZ/T15001-2008纺织常用变性淀粉浆料[S].北京:中国标准出版社,2008.
  • 8Zhu Z F, Li M L, Jin E Q. Effect of an allyl pretreatment of starch on the grafting efficiency and properties of allyl starch-g-poly ( acrylic acid) [ J ]. Journal of Applied Poly- mer Science,2009,112:2822-2829.
  • 9Lafargue D, Pontoire B, Bul6on A, et al. Structure and me- chanical properties of hydroxypropylated starch films[ J ]. Biomacrcmolecules, 2007,8 : 3950-3958.
  • 10Guan X L, Su Z X. Synthesis and characterization of fluo- rescent starch using fluorescein as fluorophore: potential polymeric temperature/pH indicators [ J ]. Polymers for Advanced Technologies ,2008,19:385-392.

二级参考文献32

  • 1郑志荣,祝志峰.聚丙烯酸酯浆料丙烯腈结构单元作用评估[J].棉纺织技术,2005,33(12):17-20. 被引量:22
  • 2刘凡,李培金,丁禹.水转印用PVA水解膜的研究[J].应用化工,2006,35(3):210-212. 被引量:1
  • 3朱林晖,丁马太.CAN引发淀粉与MMA接枝共聚反应的研究[J].功能材料,2006,37(4):615-617. 被引量:11
  • 4佘纲哲,Biochemistry of Grain,1987年,100页
  • 5江畹兰(译),Mechno Chemistry of Polymer,1982年,7页
  • 6北京有机化工厂研究所,Property and Application of Polyvinyl Alcohol,1979年,36页
  • 7Yang Liying, Sriroth K, Chollakup R, et al. Effect of plasticizers on physical property and biodegradability of starch/polycaprolactone base blend[J].大连轻工业学院学报,2002,21(2):89-95.
  • 8王树恒.生物可降解的蛋白质/淀粉基热塑性组合物[P].CN1299238A.2001.
  • 9de Carvalho A J F, Curvelo A A S, Agnelli J A M. A first insight on composites of thermoplastic starch and kaolin[J]. Carbohydrate Polymers,2001,45(2):189.
  • 10日笠慎太郎,磯ざき孝德,田中信雄.水压耘写方法及び水圧耘写用べ一スフイルム:WO,2005/039891[P].2005-05-06.

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