摘要
从苄胺和乙二醛出发 ,通过缩合、氢解脱苄等反应合成了高张力高密度笼形化合物——六乙酰基六氮杂异伍兹烷 ( HAIW) ,并经 FTIR、1H NMR、MS( CI)及元素分析等证实该化合物的结构。HAIW是合成六硝基六氮杂异伍兹烷 ( HNIW)的一种极佳中间体 ,而 HNIW是迄今为止密度和能量水平很高的高能量密度化合物。
A polycyclic caged compound with high strain and high density——hexaacetyl hexa azaisowurtzitane (HAIW) was synthesized via a two step reaction: condensation and hydrogenolysis debenzylation, starting from benzylamine and glyoxal. The structure of HAIW was confirmed by FTIR, 1H NMR, MS(CI) and elemental analysis. HAIW is good intermediate for preparing hexanitrohexaazaisowurtzitane (HNIW) which is the most promising high density compound ever studied.
出处
《化学世界》
CAS
CSCD
2000年第9期462-464,共3页
Chemical World
