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Dissolution kinetics of iron oxides in clay in oxalic acid solutions 被引量:3

Dissolution kinetics of iron oxides in clay in oxalic acid solutions
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摘要 Clay samples containing 8.15% iron oxides and 27.49% alumina were leached in oxalic acid. Leaching experiments were per-formed in aqueous solutions of oxalic acid of 0.2-2 mol/L at 40-80 C for up to 90 min. The mixed kinetic mechanism, i.e., t/τ=[(1 2X/3) (1 X)2/3 ]+b[ 1 (1 X)1/3], seemed to be the most appropriate one to fit the kinetic data of leaching iron oxides contained in clay in the aqueous oxalic acid solutions. The Arrhenius activation energy for leaching in the 1.8 mol/L oxalic acid was found to be 41.035 kJ/mol. Clay samples containing 8.15% iron oxides and 27.49% alumina were leached in oxalic acid. Leaching experiments were per-formed in aqueous solutions of oxalic acid of 0.2-2 mol/L at 40-80 C for up to 90 min. The mixed kinetic mechanism, i.e., t/τ=[(1 2X/3) (1 X)2/3 ]+b[ 1 (1 X)1/3], seemed to be the most appropriate one to fit the kinetic data of leaching iron oxides contained in clay in the aqueous oxalic acid solutions. The Arrhenius activation energy for leaching in the 1.8 mol/L oxalic acid was found to be 41.035 kJ/mol.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2012年第12期1083-1087,共5页 矿物冶金与材料学报(英文版)
关键词 CLAY iron oxides LEACHING oxalic acid KINETICS activation energy clay iron oxides leaching oxalic acid kinetics activation energy
作者简介 Corresponding author: A.S.W. Kurny E-mail: aswkurny@mme.buet.ac.bd
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