摘要
采用电感耦合等离子体-原子发射光谱法(ICP-AES)同时测定了陶瓷颜料中的镉、锌、钛、铬、铁、钙、镁等多种元素。样品经王水的缓慢溶解,再加入氢氟酸除硅。在HNO3介质中,用ICP-AES测定其中的多种元素。讨论了溶样条件、基体效应等影响因素。在选定的仪器最佳条件下,该方法测定各元素的相对标准偏差(RSD,n=12)在0.52%—3.06%之间,加标回收率在98.6%—104.3%之间。该方法分析实际样品,分析结果与其他方法一致。
The multiple elements（Cd,Zn,Ti,Cr,Fe,Ca and Mg） in ceramic pigment were simultaneously determined by inductively coupled plasma-atomic emission spectrometry（ICP-AES）. The samples were slowly dissolved by aqua regia,then Si was removed by hydrofluoric acid.The multiple elements were determined by ICP-AES in nitric acid medium.The influencing factors （dissolving conditions of samples and matrix effect） were investigated.Under the selected optimal conditions,RSD of each element ranged from 0.52%to 3.06%,and recoveries were in the range of 98.6%-104.3%.The method is applied to analysis of actual samples,analytical results agreed with the results of other method.
出处
《光谱实验室》
CAS
CSCD
2012年第4期2306-2308,共3页
Chinese Journal of Spectroscopy Laboratory
基金
国家质检总局项目(2009IK004)
关键词
电感耦合等离子体-原子发射光谱
陶瓷颜料
多种元素
Inductively Coupled Plasma-Atomic Emission Spectrometry
Ceramic Pigment
Multiple Elements
作者简介
作者简介：罗明贵（1966-），男，广西荔浦县人，高级工程师，学士.主要从事化工及矿产品检验及检测方法研究。
联系人．手机：（0）13807703937；传真：（0770）2822706；E—mail：lixiangrongll0@163．com黎香荣（1979-）。女，广西桂林市人，工程师，硕士。主要从事矿产品分析检验研究工作。
