摘要
为提高蛭石的层间距和对有机物的吸附能力,采用阳离子表面活性剂溴化十六烷基三甲铵(CTMAB)对蛭石进行改性,并研究了其对水中对硝基苯酚的去除效果。结果显示,改性蛭石对溶液中的对硝基苯酚吸附能力明显强于原蛭石;改性蛭石对溶液中的对硝基苯酚的吸附过程在30 min左右就基本达到平衡;碱性条件有利于改性蛭石吸附去除对硝基苯酚。利用扫描电镜对溴化十六烷基三甲铵(CTMAB)改性后的蛭石结构特征变化进行的分析表明,蛭石经改性后,其层间距变大,大大增加了层间对对硝基苯酚的吸附空间,从而大幅度提高蛭石对对硝基苯酚的吸附能力。
In order to improve the interlayer space of vermiculite and its adsorption capacity of organic matter GTMAB - vermiculite, cetyltrimethylammonium bromide is applied to modify vermiculite, and its removal effect on P- nitrophenal in water is also studied. The resuits show that P - nitraphenol removal rate of modified venmiculite is better than that of the original vermiculite and the adsorption process can reach the balance after 30 rains; alkaline conditions are conducive to CTMAB - vermiculite adsorption of P - nitrophenol. Structural characteristic of vemiculite and CTMAB- vermiculite has been studied through SE and the analysis indicates: interlayer space of medified vermionlite becomes larger, a larger increases in adsorption of P - nitraphenol between interlayer space, thereby dramatically the modified vermiculite adsorption capacity of P - nitrophenol can be improved.
出处
《工业安全与环保》
北大核心
2011年第12期7-8,34,共3页
Industrial Safety and Environmental Protection
基金
江苏省环境材料与环境工程重点实验室基金项目
关键词
蛭石
溴化十六烷基三甲铵
对硝基苯酚
vermiculite cetyltrimethylanwannium bromide P- nitrophenol
作者简介
唐见,男,1985年生,安徽庐江人,硕士研究生,研究方向为环境材料。