摘要
Since the discovery of BiSrCaCuO superconductor, for stabilizing and promoting the formation of high T<sub>c</sub> 2223 phase substituting a part of Bi with Pb is the most effective way. We have systematically studied the effect of the high valency cations V<sup>5+</sup>, Nb<sup>5+</sup> and Ta<sup>5+</sup> on the formation of high T<sub>c</sub> 2223 phase and found that doping any of them can