摘要
本文合成了3个新型中位分别为N,N-二甲基苯胺、对-甲氧基苯基或苯基取代的含稠合外环的硼-二吡咯亚甲基染料。研究了它们的吸收光谱、稳态荧光光谱和电化学性质;采用荧光光谱滴定方法研究了它们在强极性溶剂中对氢离子的响应;将氢离子滴加到N,N-二甲基苯胺取代的硼-二吡咯亚甲基染料(1)的CH3CN-H2O(1∶1,V/V)溶液中,其溶液的荧光显著增强;染料1在可见光激发下,可以作为酸性pH范围内检测氢离子的荧光探针。
Three new exocyclic ring-fused boron-dipyrromethene（BDP）dyes with N,N-dimethylaniline,p-methoxyphenyl or phenyl subunit at meso-position were synthesized.Their absorption,steady-state fluorescence and electrochemical properties were investigated.The spectrofluorometric titrations were performed to examine their responsive abilities to H^＋ in strong polar solvent.The dimethylanilino-substituted BDP dye 1 showed a large fluorescence enhancement upon adding H^＋ to its CH3CN-H2O（1∶1,V/V）solution.BDP 1 can be used as a fluorescent probe for H^＋ in the acidic pH range excited with visible light.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2011年第6期1177-1184,共8页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.20401009)
霍英东教育基金会(No.104013)
河南省科技厅科技攻关(No.082102210050)
河南省教育厅自然科学研究资助计划(No.2011A150023)
商丘师院重大项目培育计划立项(No.2011ZDPY02)
2010年商丘师范学院青年骨干教师资助计划资助项目
关键词
硼-二吡咯亚甲基染料
稠合外环
氢离子识别
电子转移
荧光探针
Boron-dipyrromethene（BDP）dyes
fused exocyclic rings
H＋ recognition
electron transfer
fluorescent sensor
作者简介
通讯联系人。E-mail：zshen@nju．edu．cn．xuhyun@163．com
