二维配合物[Cd_3(HBTA)_2(BIPA)_3]_n的水热合成、晶体结构和荧光性质研究(英文) 被引量：1

Hydrothermal Synthesis,Crystal Structure and Photoluminescence of a New Two-Dimensional Cadmium(Ⅱ) Complex [Cd_3(HBTA)_2(BIPA)_3]_n

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摘要 Great interest has been focused on the rapidly expanding field of the construction of novel functional metal-organic frameworks(MOFs)owing to their variety of intriguing architectures and topologies and their potential applications in The hydrothermal reactions of 5-bromoisophthalic acid（H2BIPA）,benzotriazole（HBTA） with Cd（NO3）2· 4H2O in basified solvent gave rise to a coordination polymer [Cd3（HBTA）2（BIPA）3]n（1）,which has been characterized by elemental analysis,IR and single-crystal X-ray diffraction.Complex 1 presents a two-dimensional（2D） layer network containing the edge-sharing 1D-O-Cd-O chains through repetitions of the alternating arrangement of the Cd3（CO2）6 cluster and displays strong luminescent emission at room temperature.CCDC：775284.

作者刘光祥许玉勇任小明

机构地区安庆师范学院化学化工学院

出处《无机化学学报》 SCIE CAS CSCD 北大核心 2010年第10期1885-1889,共5页 Chinese Journal of Inorganic Chemistry

基金国家自然科学基金(No.20971004) 教育部科学技术研究重点项目(No.210102)资助

关键词镉配合物晶体结构多酸配体荧光性质 cadmium（Ⅱ）complex crystal structure multicarboxylate ligand luminescence

分类号 O614.242 [理学—无机化学]

作者简介刘光祥，男，39岁，博士，教授；研究方向：功能配合物。通讯联系人。E-mail：njuliugx@gmail．com

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