摘要
研究Ti60高温钛合金在600～750℃范围内的氧化行为。氧化增重试验及XRD、SEM分析结果表明,Ti60合金在600～750℃范围内氧化0～100h条件下,由Wagner的氧化经验公式计算得氧化指数n在1～2之间,氧化激活能为256kJ/mol,氧化符合线性-抛物线混合规律。在600℃氧化100h及750℃氧化10h,氧化产物为TiO2,经750℃、100h长时间氧化后,表面有少量Al2O3生成,氧化物优先沿原始β晶界形核。氧除了会在试样表面形成氧化层外,还会向基体中扩散形成脆性富氧层,从而影响合金力学性能。随着氧化温度的升高和时间的延长,富氧层厚度增厚。
Air oxidation behavior of Ti60 alloy was studied in the temperature range from 600℃ to 750℃.In addition to the determination of the oxidation kinetics by mass gain measurements,the morphology of the scales formed was observed by SEM and the phases present in the scales were characterized by X-ray diffraction.Results show that under the condition of oxidation at 600-750℃ for 0-100 h,the oxidation exponent n is between 1 and 2 calculated by oxidation experience formula of Wagner,the total oxidation energy is 256 kJ/mol,and the oxidation kinetics follows the linear-parabolic law.When Ti60 alloy was oxidized at 600℃ for 100 h or at 750℃ for 10 h,the oxidation product is TiO2,while there was a little Al2O3 on the surface when the alloy was oxidized at 750℃ for 100 h.The oxides were preferentially formed at the grain boundaries of the alloy.Besides the oxidation layer on the sample surface,oxygen also dissolves into the matrix to form brittle oxygen-enriched layer resulting in the mechanical property change.The oxygen-enriched layer was thickened with the increase of oxidation temperature and prolonging of the oxidation time.
出处
《稀有金属材料与工程》
SCIE
EI
CAS
CSCD
北大核心
2010年第5期781-786,共6页
Rare Metal Materials and Engineering
基金
国家"973"计划(2007CB613807)
新世纪优秀人才支持计划(NCET-07-0696)
作者简介
作者简介：贾蔚菊，女，1981年生，博士，西北工业大学材料学院，陕西西安710072，电话：029—88494298，E—mail：zengwd@nwpu．edu．cn
