摘要
合成了氯化－四－（１－萘基）四苯并卟啉锰配合物［ＴＮＴＢＰＭｎ（Ⅲ）Ｃｌ］。用元素分析、紫外可见光谱、红外光声光谱、质子核磁共振谱、摩尔电导进行了表征。用循环伏安法研究了ＴＮＴＢＰＭｎ（Ⅲ）Ｃｌ的电化学性质。结果表明，锰卟啉配合物中心离子由正三价还原为正二价的半波电位为－０．５２５Ｖ，卟啉环还原的半波电位为－１．７７０Ｖ。
A kind of porphyrinmanganese(Ⅲ) complex,tetra (1 naphythyl) tetrabenzoporphyrin manganese(Ⅲ) chloride,TNTBPMn(Ⅲ)Cl,was synthesized and characterized by elementary analysis,UV spectra,infrared photoacoustic spectra, 1HNMR and molar conductances.The electrochemical behaviour of TNTBPMn(Ⅲ)Cl was investigated by cyclic voltammetry in dimethylsufoxide(DMSO).The half wave potential of [TNTBPMn(Ⅲ)] +/TNTBPMn(Ⅱ) is -0.525V, and that of TNTBP(Ⅱ)/[TNTBP(Ⅱ)] - is -1.770V.
出处
《化学研究与应用》
CAS
CSCD
1998年第6期578-582,共5页
Chemical Research and Application
基金
国家自然科学基金
关键词
萘基
四苯并卟啉
配合物
光存储材料
Tetra (1 naphythyl) tetrabenzoporphyrin,Manganese(Ⅲ),Synthesis,Cyclic voltammetry
