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离子液体[bmim]Br的制备及应用 被引量：6

Synthesis and Application of Ironic Liquid [bmim]Br
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摘要 采用一步法合成溴化1-丁基-3-甲基咪唑[bmim]Br，以红外光谱进行表征。在303.15-333．15K范围内用循环法测定了CO2在MDEA-H20及MDEA-[bmim]Br-H2O体系中的溶解度，进而考察了该体系脱碳的能力。实验结果表明[bmim]Br的添加可以提高CO2在MDEA水溶液中的溶解度，且随着压力的升高，CO2在复合溶液体系中的溶解度增大；随着温度的升高CO2溶解度降低。 A one-step synthesis bromide 1-butyl-3-methylimidazo [ bmim] Br is characterized by using the infrared spectrum. In this paper, between 303.15-333.15 K, the cycle method is used to determine the solubility of the CO2 in the MDEA-H2O and MDEA-[bmim] Br-H2O system, and then the ability of system to de-carbonization is inspected. The results show that adding of [bmim] Br in the MDEA can improve the solubility of CO2 in aqueous solution, as the pressure and the concentration of MDEA increase, solubility of CO2 in the complex solution system increases.
作者 梁蕾 宣爱国 吴元欣 王艳艳 程思
机构地区 湖北省新型反应器与绿色化学工艺重点实验室 武汉工程大学化工与制药学院
出处 《武汉理工大学学报》 CAS CSCD 北大核心 2009年第19期63-66,共4页 Journal of Wuhan University of Technology
基金 湖北省新型反应器与绿色化学工艺重点实验室开放基金(XLHX2007002) 武汉工程大学大学生校长基金
关键词 N-甲基二乙醇胺(MDEA) 溴化1-丁基-3-甲基咪唑([bmim]Br) CO2 脱碳 溶解度 bromidel-butyl-3-methylimidazo（[ bmim] Br） N-Methyldiethanolamine （MDEA） CO2 decarbonization solubility
分类号 TQ028.17 [化学工程]
作者简介 梁蕾（1984-），女，硕士生．E-mail：lianglei1219@hotmail．com
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参考文献4

二级参考文献67

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共引文献45

同被引文献44

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武汉理工大学学报
2009年 第19期

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