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VPO/SiO_2催化剂的制备及性能研究 被引量:5

Preparation and Catalytic Performance of VPO/SiO2 Catalysts
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摘要 VPO/SiO2催化剂的制备及性能研究牛童王晓来1)索继栓(中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室兰州730000)关键词VPO/SiO2催化选择氧化正丁烷顺酐分类号O643.32利用混浆钒磷混合氧化物催化剂催化正丁烷选择氧化制... お series of VPO/SiO2 catalysts were prepared using a simple method under mild conditions, and their performance was evaluated for selective oxidation of nbutane to maleic anhydride. The results indicated that these catalysts exhibit good catalytic activities. The highest selectivity to maleic anhydride of 56.6% was obtained at 320℃ reaction temperature. The effects of P/V ratio on the catalytic performance were also investigated, with the increase of the P/V ratio from 0.9 to 1.5, the selectivity to maleic anhydride was increased from 17.0% to 46.6%.
出处 《分子催化》 EI CAS CSCD 北大核心 1998年第3期234-236,共3页 Journal of Molecular Catalysis(China)
关键词 VPO 选择氧化 正丁烷 顺酐 催化剂 制备 VPO/SiO2, Catalytic selective oxidation, nButane, Maleic anhydride
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