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氧化絮凝复合床水处理新技术的研究 被引量:27

Study of the New OxideFlocculation Reactor Technique for Wastewater Treatment
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摘要 提出了氧化絮凝复合床水处理新技术.由复合床内的两个主电极之间充填高效、无毒而廉价的颗粒状专用材料、催化剂(或催化手段)及一些辅助剂构成.在一定的物理化学操作条件下,废水中的污染物会发生如催化氧化分解、混凝、吸咐、络合、置换等作用而迅速被去除.以含苯酚和三氯乙醛模拟废水为研究对象,研究了这种水处理新技术去除废水中有机物的机理,主要是基于生成H2O2并迅速产生羟基自由基对水中有机物的强氧化作用.用自旋捕集ESR法测出了在复合床处理废水过程中不断产生的·OH.最后对城市生活污水、印染和医药等实际工业废水进行了处理试验。 The new oxideflocculation reactor (OFR) technique for wastewater treatment was successfully developed. The OFR is filled with the high effect nontoxic special material, catalyst and other auxiliary ingredients between the main electrodes.Under physicalchemical optimal condition, inorganic and organic contaminants in wastewater are rapidly removed by subjecting to oxidationreduction, coagulation, adsorption, complexation, replacement and so on in the OFR Two types of organic pollutants, phenol and chloral hydrate as the objects of the catalytic degradation mechanism with the OFR technique were studied The results indicate that is actually the oxidation of hydroxyl radical (·OH) which can be produced rapidly from the first yielded H2O2 in the OFR·OH in the treating process of the OFR with the method of spintrapping ESR was discovered Finally, the treatment for various wastewater(domestic sewage, printing and dyeing wastewater, pharmaceutical industry wastewater ) with the OFR were investigated 
出处 《中山大学学报(自然科学版)》 CAS CSCD 北大核心 1998年第4期80-84,共5页 Acta Scientiarum Naturalium Universitatis Sunyatseni
基金 广东省科委"九五"攻关资助项目
关键词 氧化絮凝复合床 水处理 新技术 废水处理 oxideflocculation reactor (OFR), wastewater treatment, new technique
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参考文献5

  • 1胡春,王怡中,汤鸿霄.多相光催化氧化的理论与实践发展[J].环境科学进展,1995,3(1):55-64. 被引量:173
  • 2团体著者,水与废水监测分析方法(第3版),1989年
  • 3乌锡康,有机污染治理技术,1989年
  • 4徐荃,分析化学,1988年,16卷,7期,595页
  • 5张建中,化学通报,1988年,1期,27页

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