摘要
The binuclear Zn(Ⅱ) complex [Zn2(L)2(Mf)2] with 2-hydroxyacetophenone benzoylhydrazone(H2L) and monodentate N-heterocycle,morphine(Mf) has been synthesized and characterized by elemental analysis,IR,UV,molar conductivity,TG and X-ray diffraction structural analysis.Crystal data: monoclinic,space group P21/n with a=1.263 9(6) nm,b=1.085 2(4) nm,c=1.313 4(5) nm,β=92.16(2)°,V=1.800(1) nm3,Z=2,Dc=1.493 g.cm-3,μ= 1.388 mm-1,F(000) =840,and final R =0.038 4,wR =0.087 9.The two Zn (Ⅱ) centers in the centrosymmetric binuclear complex are bridged by phenolic oxygen atoms with Zn…Zn separation of 0.315 0(1) nm.The coordina-tion geometry of each Zn(Ⅱ) atom is trigonal bipyramidal.The fluorescence activities of ligand and the complex were also studied.
The binuclear Zn（Ⅱ） complex [Zn2（L）2（Mf）2] with 2-hydroxyacetophenone benzoylhydrazone （H2L） and monodentate N-heterocycle, morphine （Mf） has been synthesized and characterized by elemental analysis, IR, UV, molar conductivity, TG and X-ray diffraction structural analysis. Crystal data： monoclinic, space group P21/n with a=1.263 9（6） nm, b=1.085 2（4） nm, c=1.313 4（5） nm,β=92.16（2）°, V=1.800（1） nm^3, Z=2, Dc=1.493 g·cm^-3,μ= 1.388 mm^-1, F（000）=840, and final R=0.038 4, wR=0.087 9. The two Zn（ll） centers in the centrosymmetric binuclear complex are bridged by phenolic oxygen atoms with Zn...Zn separation of 0.315 0（1） nm. The coordination geometry of each Zn（Ⅱ） atom is trigonal bipyramidal. The fluorescence activities of ligand and the complex were also studied. CCDC： 712643.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2009年第5期910-914,共5页
Chinese Journal of Inorganic Chemistry
基金
福建师范大学本科生“课外科技计划”项目(No.BKL2008031)
作者简介
通讯联系人。陈小华，女，30岁，讲师；研究方向：配合物结构化学。E-mail：xiaohuachen03@163．com
