摘要
A novel polyethylene glycol （PEG）-200-based dicationic acidic ionic liquid （PEG200-DAIL） was used to synthesize HMX from DPT by nitrolysis with N2O5. It was found that either N2O5 or PEGzoo-DAIL could improve the yield. Furthermore, the combined use of PEG200-DAIL and N2O5 could increase the yield of HMX to 64% with the used quantity of HNO3 decreased dramatically.
A novel polyethylene glycol （PEG）-200-based dicationic acidic ionic liquid （PEG200-DAIL） was used to synthesize HMX from DPT by nitrolysis with N2O5. It was found that either N2O5 or PEGzoo-DAIL could improve the yield. Furthermore, the combined use of PEG200-DAIL and N2O5 could increase the yield of HMX to 64% with the used quantity of HNO3 decreased dramatically.
基金
support from National Basic Research(973) Program of China(No.613740101)
作者简介
Corresponding author. E-mail address： lucx@njust.edu.cn （C.X. Lv）.
