摘要
以γ－（乙二胺基）丙基三乙氧基硅烷为偶联剂合成了Ｃ６０键合硅胶固定相；用元素分析法测定得到该固定相的Ｃ６０键合量为５７．５７μｍｏｌ／ｇ。考察了多环芳烃和杯芳烃在Ｃ６０键合硅胶固定相上的分离，多环芳烃在该固定相上的洗脱顺序与ＯＤＳ固定相相似；杯芳烃的洗脱顺序为杯［８］、杯［４］和杯［６］芳烃。
C_60 was chemically attached to γ(ethylenediamino) propylsilyl bonded silica as a stationary phase for liquid chromatography. The new stationary phase was used to investigate the separations of polycyclic aromatic hydrocarbons (PAHs) and tert butylcalix arenes. The elution order of PAHs was found to be similar to that on octadecylsilica (ODS); the elution order of tert butylcalix arenes was found to be tert butylcalixarene, tert butylcalixarene and tert butylcalixarene with 1%( V/V) isopropanol/cyclohexane as a mobile phase.
出处
《色谱》
CAS
CSCD
北大核心
1998年第2期115-117,共3页
Chinese Journal of Chromatography
关键词
C60键合硅胶
固定相
杯芳烃
多环芳烃
LC
硅胶
liquid chromatography, C_60 bonded silica stationary phase, calixarenes, polycyclic aromatic hydrocarbons
