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酸碱滴定法测定马来酸酐接枝氯化聚丙烯的接枝率 被引量:18

STUDY ON THE GRAFTNG YELD OF MALEC ANHYDRDE GRAFTED CHLORNATED POLYPROPYLENE BY NEUTRALZATON TTRATON
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摘要 讨论了测定马来酸酐接枝氯化聚丙烯[(PP-C)-g-MAH]接枝率的重要意义,分析了几种接枝率测定方法的优缺点。针对(PP-C)-g-MAH的特殊结构,研究了一种利用酸碱滴定法准确测定接枝物酸值的测定方法。通过考察(PP-C)-g-MAH主链上叔碳氯脱除量的影响因素,确定了接枝率测定方法的工艺参数,并对误差情况进行分析。 The important significance of measuring the grafting rate of maleic anhydride grafted chlorinated polypropylene [ (PP-C)-g-MAH] was discussed, and the merits and demerits of several methods for measuring the grafting rate were analyzed. A method for exactly measuring the acid value of (PP-C)-g-MAH by neutralization titration was researched according to it's special structure. The parameters of method for measuring the grafting rate was established by investigating influence factors of dechlorinating of (PP-C)-g-MAH main chain tertiary carbon chlorin and the error conditions were analysed.
出处 《工程塑料应用》 CAS CSCD 北大核心 2009年第1期52-55,共4页 Engineering Plastics Application
关键词 马来酸酐 接枝 氯化聚丙烯 酸碱滴定 接枝率 maleic anhydride, graft, chlorinated polypropylene, neutralization titration, grafting yield
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